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(C10H6(P(C6H5)2))2Ru(OOCCH3)2 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 114818-52-9 Structure
  • Basic information

    1. Product Name: (C10H6(P(C6H5)2))2Ru(OOCCH3)2
    2. Synonyms:
    3. CAS NO:114818-52-9
    4. Molecular Formula:
    5. Molecular Weight: 841.845
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 114818-52-9.mol
    9. Article Data: 4
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (C10H6(P(C6H5)2))2Ru(OOCCH3)2(CAS DataBase Reference)
    10. NIST Chemistry Reference: (C10H6(P(C6H5)2))2Ru(OOCCH3)2(114818-52-9)
    11. EPA Substance Registry System: (C10H6(P(C6H5)2))2Ru(OOCCH3)2(114818-52-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 114818-52-9(Hazardous Substances Data)

114818-52-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 114818-52-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,8,1 and 8 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 114818-52:
(8*1)+(7*1)+(6*4)+(5*8)+(4*1)+(3*8)+(2*5)+(1*2)=119
119 % 10 = 9
So 114818-52-9 is a valid CAS Registry Number.

114818-52-9Downstream Products

114818-52-9Relevant articles and documents

Dynamic Kinetic Asymmetric Reductive Amination: Synthesis of Chiral Primary β-Amino Lactams

Lou, Yazhou,Hu, Yutao,Lu, Jiaxiang,Guan, Fanfu,Gong, Gelin,Yin, Qin,Zhang, Xumu

supporting information, p. 14193 - 14197 (2018/10/15)

A highly efficient ruthenium-catalyzed asymmetric reductive amination (ARA) of racemic β-keto lactams with molecular hydrogen and ammonium salts is disclosed for the synthesis of enantiomerically pure primary amino lactams through dynamic kinetic resolution (DKR). By this approach, a range of syn primary β-amino lactams were obtained in high yields with high chemo-, enantio-, and diastereoselectivity (up to 98 % yield, 99 % ee, >20:1 d.r., syn products). The utility of the products has been demonstrated by rapid access to a key synthetic intermediate towards biologically active drug molecules. Meanwhile, mechanistic studies and control experiments indicate that the reaction may proceed through the hydrogenation of an iminium intermediate.

METHOD FOR PRODUCING A RUTHENIUM COMPLEX

-

Page/Page column 6, (2010/04/23)

Provided is a method for producing a ruthenium complex comprises the step of reacting a ruthenium compound represented by general formula (1): [in-line-formulae][RuX(L)(PP)]X ??(1),[/in-line-formulae] wherein Ru represents a ruthenium atom; X represents a halogen atom; L represents an arene; and PP represents an optically active bisphosphine, with a carboxylate salt represented by general formula (2): [in-line-formulae]R1CO2M ??(2),[/in-line-formulae] wherein M represents a monovalent cation; and R1 represents a group selected from the group consisting of alkyl groups, haloalkyl groups, phenyl groups optionally having a substituent(s), 1-aminoalkyl groups and 1-amino-1-phenylalkyl groups, to produce a ruthenium complex represented by general formula (3): [in-line-formulae]Ru(OCOR1)2(PP) ??(3),[/in-line-formulae] wherein R1 represents the group selected from the group consisting of alkyl groups, haloalkyl groups, phenyl groups optionally having a substituent(s), 1-aminoalkyl groups and 1-amino-1-phenylalkyl groups; and PP represents the optically active bisphosphine.

Enantioselective hydrogenation of tiglic acid in methanol and in dense carbon dioxide catalyzed by a ruthenium-BINAP complex substituted with OCF 3 groups

Dong, Xing,Erkey, Can

, p. 73 - 81 (2008/10/09)

A fluorinated analog of the 2,2′-bis(diphenylphosphino)-1,1′- binaphthyl (BINAP) ligand was synthesized with OCF3-substitution of the aryl groups in BINAP skeleton (p-OCF3-BINAP). Ruthenium complexes of both BINAP (Ru-BINAP) and (p-OCF3)-BINAP (Ru-[(p-OCF3)-BINAP]) were also synthesized and investigated as catalysts for hydrogenation of tiglic acid in methanol. Typically, Ru-[(p-OCF3)-BINAP] had lower activity but had higher enantioselectivity at high hydrogen pressures than Ru-BINAP at the same condition. The effect of OCF3 groups on the catalytic properties was discussed on the basis of NMR spectra and kinetic data. Ru-[(p-OCF 3)-BINAP] was found to have sufficiently high solubility in dense CO2 for homogeneous catalytic reactions and was investigated for hydrogenation of tiglic acid in CO2. The results showed that CO 2 had a great influence on both activity and enantioselectivity. Addition of methanol to CO2 was found to increase the enantioselectivity.

Asymmetrische Katalysen. LXXXII. Enantioselektive Hydrierung von 4-Oxoisophoron

Brunner, Henri,Fisch, Konrad

, p. 71 - 75 (2007/10/02)

Enantioselective hydrogenation of 4-oxoisophorone 1, catalysed by BINAP-RuII complexes, gives the corresponding saturated diketone 2 in 80percent chemical yield and 50percent enantiomeric excess.By repeated crystallisation from petroleum ether/

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