114935-91-0

Basic information

• Product Name: 5-phenylthio-2-carbamoy-1H-1,4-benzodiazepine
• CAS NO: 114935-91-0
• Molecular Weight: 295.365
• Mol File: 114935-91-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-phenylthio-2-carbamoy-1H-1,4-benzodiazepine(CAS DataBase Reference)
• NIST Chemistry Reference: 5-phenylthio-2-carbamoy-1H-1,4-benzodiazepine(114935-91-0)
• EPA Substance Registry System: 5-phenylthio-2-carbamoy-1H-1,4-benzodiazepine(114935-91-0)

Safety Data

• Hazardous Substances Data: 114935-91-0(Hazardous Substances Data)

Upstream product

• 114935-95-4 4-chloro-8-methylsulfonylquinoline 
• 930-69-8 sodium thiophenolate 
• 114935-78-3 4-azido-8-methylsulfonylquinoline 

Relevant articles and documents

THE FIRST EXAMPLES OF ISOLATED N-UNSUBSTITUTED 1H-1,4-BENZODIAZEPINES

The photolysis in the presence of sodium methoxide of the 4-azidoquinolines (5a-g) having a carbonyl group or its analogue in the 2- or 8-position resulted in ring expansion to give the stable N-unsubstitued 1H-1,4-benzodiazepines (6a-g).These were assumed to be stabilized by intramolecular hydrogen bonding between the NH and the 2- or 9-acyl groups.It is known that the N-unsubstituted 1H-1,4-benzodiazepines having no acyl group are too unstable to be isolated.KEYWORDS---- 4-azidoquinoline; photolysis; ring expansion; N-unsubstituted 1H-1,4-benzodiazepine; hydrogen bonding