114969-14-1Relevant articles and documents
Highly stereoselective monofluoroolefination: Facile access to (E)-α-fluorinated arylvinyl sulfones from trifluoromethyl α-fluorinated arylsulfonyl gem-diols
Fang, Xiang,Zhou, Jun,Wang, Wang,Yang, Xueyan,Wu, Fanhong
, (2020)
An excellent stereoselective direct synthesis of trisubstituted (E)-α-fluorinated arylvinyl sulfones employing trifluoromethyl α-fluorinated arylsulfonyl gem-diols and aryl aldehydes under mild reaction conditions has been developed, which affords α-fluorinated arylvinyl sulfones in high yields with E-isomer only. The desired products can be further transformed into more useful fluoroolefins through debenzenesulfonyl process.
Julia olefination as a general route to phenyl (α-fluoro)vinyl sulfones
He, Maggie,Ghosh, Arun K.,Zajc, Barbara
body text, p. 999 - 1004 (2009/04/04)
Mild and efficient synthesis of phenyl (α-fluoro)vinyl sulfones via condensation of aldehydes and a ketone with a novel benzothiazolyl based bis-sulfone reagent is reported and this proceeds with moderate to good Z-stereoselectivity. Georg Thieme Verlag Stuttgart.
