115162-51-1Relevant articles and documents
Picosecond Absorption Studies on the Excited State of (μ-Oxo)bis
Guest, C. R.,Straub, K. D.,Hutchinson, J. A.,Rentzepis, P. M.
, p. 5276 - 5280 (1988)
We have measured the kinetics and spectra of the intermediates of (μ-oxo)bis in various solvents.The spectra of the intermediate species were measured at various intervals of time from -100 to 4.3 ns after excitation with a 532- or 355-nm 25-ps pulse.The intermediate state, possibly a cation radical, was assigned to a monomer that forms the photodissociated pair TPPFeII+ + TPPFeIII-O- and yields a small amount of disproportionation reaction products, FeIITPP and TPPFeIV=O.t