116-85-8

Basic information

• Product Name: Celliton Fast Pink B
• Synonyms: 10-Anthracenedione,1-amino-4-hydroxy-9;1a-4oa;1-amino-4-hydroxy-10-anthracenedione;1-amino-4-hydroxy-9,10-anthracenedione;1-Amino-4-hydroxyanthra-9,10-quinone;1-Amino-4-hydroxy-anthrachinon;1-amino-4-hydroxy-anthraquinon;1-amino-4-hydroxyanthraquinone(ci60710)
• CAS NO: 116-85-8
• Molecular Formula: C₁₄H₉NO₃
• Molecular Weight: 239.23
• EINECS: 204-163-0
• Product Categories: Anthraquinones, Hydroquinones and Quinones;Aminoanthraquinones;Anthraquinones;Hydroxyanthraquinones
• Mol File: 116-85-8.mol
• Article Data: 22

Chemical Properties

• Melting Point: 207-209 °C
• Boiling Point: 381.88°C (rough estimate)
• Flash Point: 262.748 °C
• Appearance: Deep purple to dark brown/Crystalline Powder
• Density: 1.2326 (rough estimate)
• Vapor Pressure: 4.67E-11mmHg at 25°C
• Refractive Index: 1.4700 (estimate)
• PKA: 7.38±0.20(Predicted)
• Water Solubility: Soluble in water, ethanol, acetone, benzene.
• CAS DataBase Reference: Celliton Fast Pink B(CAS DataBase Reference)
• NIST Chemistry Reference: Celliton Fast Pink B(116-85-8)
• EPA Substance Registry System: Celliton Fast Pink B(116-85-8)

Safety Data

• Hazard Codes: Xn
• Statements: 68-65-40-33
• Safety Statements: 36/37-24/25
• RTECS: CB5600000
• TSCA: Yes
• Hazardous Substances Data: 116-85-8(Hazardous Substances Data)

Usage

Chemical Properties

deep purple to dark brown crystalline powder

Uses

The use of the inclusion complex of 1-amino-4-hydroxyanthraquinone (AHA) in the internal cavity of β-cyclodextrin confers increased sensitivity, selectivity and detection limit, and allows the determination of 10-70 ng ml-1 beryllium, compared to 60-500 ng ml-1 in the absence of the cyclodextrin.

Safety Profile

Poison by intravenous route. Moderately toxic by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx,.

Properties and Applications

blue light pink to red blue light. Soluble in acetone, ethanol, benzene and linseed oil. The strong sulfuric acid to dark yellow, diluted for brown. Used in vinegar fiber, three vinegar, polyamide, polyester fiber, acrylic dyeing, also can be used for sheep and plastic color. Levelness and promote good rate. Standard Ironing Fastness Light Fastness Persperation Fastness Washing Fastness Fading Stain Fading Stain Fading Stain ISO 4 2 5-6 5 5 3-4 4

Standard

Ironing Fastness

Fading

Stain

ISO

4

Purification Methods

Purify it by TLC on SiO2 gel plates (0.75mm thick) using toluene/acetone (9:1) as eluent. The main band is scraped off and extracted with MeOH. The solvent is evaporated, and the dye is dried in a drying pistol [Land et al. J Chem Soc, Faraday Trans 1 72 2091 1976]. It has also been recrystallised from aqueous EtOH. [Beilstein 14 H 268, 14 I 503, 14 II 168, 14 III 652, 14 IV 891.]

InChI:InChI=1/C14H9NO3/c15-9-5-6-10(16)12-11(9)13(17)7-3-1-2-4-8(7)14(12)18/h1-6,16H,15H2

Upstream product

• 85-44-9 phthalic anhydride 
• 123-30-8 4-amino-phenol 
• 82-34-8 1-nitroanthraquinone 
• 82-45-1 1-amino-9,10-anthracenedione 
• 83206-61-5 5-dimethylaminoanthra<1,9-c,d>isoxazol-6-one 
• 17648-03-2 9,10-Dihydroxy-2,3-dihydro-anthracene-1,4-dione 
• 57-14-7 N,N-Dimethylhydrazine 
• 70730-89-1 6H-anthra<1,9-cd>isoxazol-6-one 
• 7664-93-9 sulfuric acid 
• 13460-50-9 metaboric acid 
• 193-79-3 anthra[1,9-cd;4,10-c',d']diisoxazole 
• 81-62-9 1-amino-4-bromo-9,10-anthracenedione 
• 56613-39-9 1-hydroxylaminoanthraquinone 
• 81-64-1 1,4-dihydroxy-9,10-anthracenedione 

Downstream Products

• 7323-62-8 4-Acetylamino-1-hydroxy-9,10-anthracenedione 
• 116-82-5 1-amino-2-bromo-4-hydroxyanthraquinone 
• 129-43-1 1-hydroxyanthraquinone 
• 81-64-1 1,4-dihydroxy-9,10-anthracenedione 
• 6373-16-6 1-methylamino-4-hydroxyanthraquinone 
• 24929-02-0 1-amino-4-hydroxy-9,10-dioxo-9,10-dihydroanthracene-2-sulfonic acid 
• 6313-46-8 1-amino-4-hydroxy-2-mercapto-anthraquinone 
• 65121-98-4 (4-hydroxy-9,10-dioxo-9,10-dihydro-[1]anthryl)-carbamic acid ethyl ester 
• 39774-73-7 1-amino-4-p-tolylaminoanthraquinone 
• 112128-38-8 1-(4-Chloro-phenyl)-3-(4-hydroxy-9,10-dioxo-9,10-dihydro-anthracen-1-yl)-urea 
• 112128-55-9 C₂₈H₁₇Cl₂N₃O₅ 
• 4395-65-7 oracet blue 2R 
• 87367-05-3 1-(3-Diethylaminopropionamido)-4-hydroxy-9,10-anthracenedione 
• 1310827-72-5 4-(4-amino-9,10-dioxo-9,10-dihydroanthracen-1-ylamino)phenyl methacrylate 

Relevant articles and documents

A facile method for preparing substituted 1-aminoanthraquinones

An efficient and simple preparation of α-substituted aminoanthraquinones using 2,2,-dialkoxyethylamines is described.

Antitumor Agents-CLXVII. Synthesis and structure-activity correlations of the cytotoxic anthraquinone 1,4-bis-(2,3-epoxypropylamino)-9,10-anthracenedione, and of related compounds

1,4-Bis-(2,3-epoxypropylamino)-9,10-anthracenedione (3) was synthesized in this laboratory and was found to be a potent antitumor agent. Derivatives of this compound containing anthraquinone, naphthoquinone, and quinone skeletons were also prepared and evaluated for in vitro cytotoxic activity in several cell lines. These molecules were designed as bifunctional antitumor agents with the potential to act as (1) intercalating agents due to their planar backbones, and (2) alkylating agents due to the presence of alkylating moieties in their side chains. Compounds with an anthraquinone skeleton and propylamino side chains containing epoxides or halohydrins as the alkylating species showed greater activity than similar compounds with naphthoquinone or quinone skeletons. Compounds without these alkylating functionalities (e.g., with alkene or amino groups) were generally inactive. Hydroxy substitution on the planar skeleton in conjunction with alkylating side chains gave compounds with the most potent cytotoxic activity. The position of the hydroxy groups and side chains could be varied without substantially affecting activity. Activity was retained when an epoxypropyloxy side chain was substituted for the epoxypropylamino side chain in the parent compound.

1-Amino-4-(4-hydroxyalkylphenyl)- and 1-Amino-4-(ω-hydroxyalkoxy)-9,10-antraquinones for Photochromic Methacrylate Polymers

-