116027-50-0

Basic information

• Product Name: 1,2-diphenyl-N,N'-di-o-tolylethane-1,2-diamine
• Synonyms: 1,2-diphenyl-N,N'-di-o-tolylethane-1,2-diamine
• CAS NO: 116027-50-0
• Molecular Weight: 392.544
• Mol File: 116027-50-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2-diphenyl-N,N'-di-o-tolylethane-1,2-diamine(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-diphenyl-N,N'-di-o-tolylethane-1,2-diamine(116027-50-0)
• EPA Substance Registry System: 1,2-diphenyl-N,N'-di-o-tolylethane-1,2-diamine(116027-50-0)

Safety Data

• Hazardous Substances Data: 116027-50-0(Hazardous Substances Data)

Upstream product

• 10228-77-0 N-(o-methylbenzylidene)aniline 
• 34143-86-7 N-((E)-benzylidene)-o-toluidine 
• 328110-37-8 N,N'-(1,2-diphenylethane-1,2-diylidene)bis(2-methylaniline) 
• 95-46-5 2-methylphenyl bromide 
• 951-87-1 meso-1,2-diphenyl-1,2-diaminoethane 
• 3144-16-9 (1S)-10-camphorsulfonic acid 
• 134-81-6 benzil 
• 95-53-4 o-toluidine 

Downstream Products

• 1449578-34-0 C₂₉H₂₇N₂⁽¹⁺⁾*BF₄^(1-) 
• 1449578-31-7 C₂₉H₂₇N₂⁽¹⁺⁾*Cl^(1-) 

Relevant articles and documents

A Highly Stereoselective Metal-Free Hydrogenation of Diimines for the Synthesis of Cis -Vicinal Diamines

A highly stereoselective metal-free hydrogenation of vicinal diimines has been successfully realized for the first time using 5-10 mol % of Piers borane as a catalyst under mild conditions, and a variety of cis-1,2-diamines were obtained in 92-99% yields.

Probing the relevance of NHC ligand conformations in the Ru-catalysed ring-closing metathesis reaction

Cat power: Judicious backbone substitution of N-heterocyclic carbenes (NHCs) leads to stable Ru metathesis catalysts with frozen NHC conformations. This finding not only permits the isolation of complexes that are among the most active catalysts in the ring-closing metathesis of hindered olefins (see graphic; Ts=p-toluenesulfonyl), but also provides fundamental mechanistic insights on the role of N-aryl substituent conformations on catalyst activity. Copyright