116139-10-7

Basic information

• Product Name: (1S,2R,6R)-2-Methoxy-bicyclo[4.1.0]hept-3-ene
• Synonyms: (1S,2R,6R)-2-Methoxy-bicyclo[4.1.0]hept-3-ene
• CAS NO: 116139-10-7
• Molecular Weight: 124.183
• Mol File: 116139-10-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R,6R)-2-Methoxy-bicyclo[4.1.0]hept-3-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,6R)-2-Methoxy-bicyclo[4.1.0]hept-3-ene(116139-10-7)
• EPA Substance Registry System: (1S,2R,6R)-2-Methoxy-bicyclo[4.1.0]hept-3-ene(116139-10-7)

Safety Data

• Hazardous Substances Data: 116139-10-7(Hazardous Substances Data)

Upstream product

• 10034-09-0 1-methoxy-1,3-butadiene 
• 2781-85-3 cyclopropene 

Relevant articles and documents

THE STEREOCHEMISTRY OF DIELS-ALDER REACTIONS OF CYCLOPROPENES

The stereochemistry of the Diels-Alder reactions of 3 cyclopropenes was determined unequivocally by X-ray and NOE studies.Tetrachlorocyclopropene yields exo-adducts with (E)-1-R-1,3-butadiene (R=OCH3, OCOCH3, OSiMe3), with 1,4-diphenylbutadiene and with furan. 1,2-bromochlorocyclopropene yields with (E)-1-R-butadienes (R=OCH3, OSiMe3) endo:exo-adducts in a ratio of 9:1.Cyclopropene + 1-methoxybutadiene yield only the endo-adduct.