1161924-31-7

Basic information

• Product Name: hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel
• CAS NO: 1161924-31-7
• Molecular Weight: 765.498
• Mol File: 1161924-31-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel(CAS DataBase Reference)
• NIST Chemistry Reference: hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel(1161924-31-7)
• EPA Substance Registry System: hydrido(2-diphenylphosphanyl)-2-thiophenolato[P,S]-1,3-bis[(diphenylphosphanyl)-propane]nickel(1161924-31-7)

Safety Data

• Hazardous Substances Data: 1161924-31-7(Hazardous Substances Data)

Upstream product

• 28069-69-4 tetrakis(trimethylphosphine)nickel⁽⁰⁾ 
• 1161924-37-3 (3-diphenylphosphanyl)-2-thionaphthol 
• 6737-42-4 1,3-bis-(diphenylphosphino)propane 

Downstream Products

• 15629-49-9 bis(1,3-bis(diphenylphosphino)propane)nickel⁽⁰⁾ 
• 14897-21-3 bis(2-diphenylphosphanyl)thiophenolato[P,S]nickel 
• 1161924-36-2 (2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel 

Relevant articles and documents

Syntheses and properties of molecular nickel(II) hydride, methyl, and nickel(I) complexes supported by trimethylphosphane and (2-diphenylphosphanyl)thiophenolato and -naphtholato ligands

(2-Diphenylphosphanyl)thiophenol (P^pSH) or (3-diphenylphosphanyl)-2-thionaphthol (P^nSH) react with Ni(PMe3)4 to form NiH(P^pS)(PMe3)2 (1) or NiH(P^nS)(PMe3)2 (2). 1,3-Bis(diphenylphosphanyl)propane (P^P) replaces the monodentate phosphane ligands to give NiH(P^pS)(P^P) (3). NiMe(OMe)(PMe3) or NiMe2(PMe3)3 react with P^pSH to form NiMe(P^pS)(PMe3) (4) and NiMe(P^pS)(PMe3)2 (5), respectively, and P^nSH affords NiMe(P^nS)(PMe3)2 (6), NiMe(P^nS)(PMe3) (7). Dissociation of PMe3 ligands induces transformation of 1 to Ni(P^pS)(PMe3)2 (8) and Ni(P^pS)2. Crystal and molecular structures are given for 1, 5-8, and dynamic solution spectra (NMR, EPR) are discussed.