116703-26-5

Basic information

• Product Name: 6,7-bis(allyloxy)-4-methyl-2H-chromen-2-one
• Synonyms: 6,7-bis(allyloxy)-4-methyl-2H-chromen-2-one
• CAS NO: 116703-26-5
• Molecular Formula: C16H16O4
• Molecular Weight: 272.29584
• Mol File: 116703-26-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 6,7-bis(allyloxy)-4-methyl-2H-chromen-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 6,7-bis(allyloxy)-4-methyl-2H-chromen-2-one(116703-26-5)
• EPA Substance Registry System: 6,7-bis(allyloxy)-4-methyl-2H-chromen-2-one(116703-26-5)

Safety Data

• Hazardous Substances Data: 116703-26-5(Hazardous Substances Data)

Upstream product

• 529-84-0 6,7-dihydroxy-4-methylcoumarin 
• 106-95-6 allyl bromide 

Relevant articles and documents

Studies in Synthesis of Furocoumarins: Part XXVIII - Synthesis of Difuranocoumarins

6,7-Diallyloxy-4-methylcoumarin (I) on Claisen migration gives 8-allyl-9-hydroxy-2,7-dimethyldihydrofuranobenzopyran-5(H)-one (IIa).The structure of IIa has been confirmed by spectral data (UV, PMR) and IIa is found to be identical (m.m.p., co-TLC) with a product synthesised unambiguously starting from 6,7-diacetoxy-4-methylcoumarin.Product IIa on cyclisation with H2SO4 gives a tetrahydrodifurano derivative (III) which on dehydrogenation over 10percent Pd/C furnishes the difurano derivative (IV).Structures of all these compounds have been confirmed by their PMR spectra.