117637-11-3Relevant articles and documents
ELECTRONIC STRUCTURE AND REACTIVITY OF 1-OXASPIROALKANES
Kas'yan, L.I.,Gorb, L.G.,Galafeeva, M.F.,Stepanova, N.V.,Minaev, E.N.,Dryuk, V.G.
, p. 320 - 326 (2007/10/02)
The behavior of the epoxides of methylenecycloalkanes (1-oxaspiroalkanes) in reaction with methanol was studied.It was shown that the direction of the reaction depends on the nature of the medium; in an alkaline medium opening of the epoxide ring takes place regiospecifically according to the Krasuskii rule, and in an acidic medium it takes place mainly in the reverse direction.The reactivity of the epoxides and its dependence on the nature of the acyclic fragment were studied by quantum-chemical calculation and kinetic investigations.
