1177-35-1

Basic information

• Product Name: 1,3,5-Triazine, 2,4,6-tris(4-methylphenoxy)-
• CAS NO: 1177-35-1
• Molecular Formula: C24H21N3O3
• Molecular Weight: 399.449
• Mol File: 1177-35-1.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 1,3,5-Triazine, 2,4,6-tris(4-methylphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Triazine, 2,4,6-tris(4-methylphenoxy)-(1177-35-1)
• EPA Substance Registry System: 1,3,5-Triazine, 2,4,6-tris(4-methylphenoxy)-(1177-35-1)

Safety Data

• Hazardous Substances Data: 1177-35-1(Hazardous Substances Data)

Usage

Chemical structure

A trisubstituted 1,3,5-triazine derivative

Common use

Herbicide

Herbicidal activity

Strong

Application

Control of weeds in agricultural settings

Effectiveness

Against a wide range of broadleaf and grassy weeds

Inhibition mechanism

Inhibits the growth of unwanted plants

Additional studies

Potential applications in the pharmaceutical industry for drug development

Safety concerns

May pose risks to human health and the environment if not properly managed

Handling

Requires caution and proper management

Upstream product

• 106-44-5 p-cresol 
• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 1192-96-7 potassium p-cresolate 
• 1121-70-6 sodium 4-methylphenoxide 
• 1124-58-9 p-tolylcyanate 
• 622-79-7 benzyl azide 

Downstream Products

• 108-88-3 toluene 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 
• 104-85-8 para-methylbenzonitrile 
• 63379-16-8 1-propyl (4-methylphenyl)carbamate 
• 4409-83-0 4-deuteriotoluene 
• 620-84-8 4-methyldiphenylamine 
• 4316-53-4 diphenyl(p-tolyl)amine 
• 3077-16-5 4-(4-methylphenyl)morpholine 
• 4714-21-0 4-methylstilbene 
• 27331-34-6 1-(4-methylphenyl)naphthalene 
• 644-08-6 4-Methylbiphenyl 
• 167283-32-1 N-(p-tolyl)indole 
• 106-49-0 p-toluidine 
• 79922-91-1 Benzyl-(4,6-bis-p-tolyloxy-[1,3,5]triazin-2-yl)-amine 

Relevant articles and documents

Microwave assisted synthesis of triaryl cyanurates

Rapid synthesis of triaryl cyanurates(2,4,6-triaryloxy-1,3,5-triazine) was carried out by reacting cyanuric chloride with the sodium salt of hydroxyaryl compounds in water using focused microwaves. Environmentally friendly procedure and isolation of pure products in excellent yields are important features of this method.

Nickel-Catalyzed Synthesis of N-(Hetero)aryl Carbamates from Cyanate Salts and Phenols Activated with Cyanuric Chloride

A simple and efficient domino reaction has been designed and employed for the one-pot synthesis of N-(hetero)aryl carbamates through the reaction between alcohols and in-situ produced (hetero)aryl isocyanates in the presence of a nickel catalyst. The phenolic C?O bond was activated via the reaction of phenol with cyanuric chloride (2,4,6-trichloro-1,3,5-triazine (TCT)) as an inexpensive and readily available reagent. This strategy provides practical access to N-(hetero)aryl carbamates in good yields with high functional groups compatibility.

Attempt to Synthesize Hindered 2,4,6-Tri-Aryloxy-s-Triazines: Bis(2,4-di-tert-Butylphenyl) Carbonate – Crystal Structure

Some less hindered 2,4,6-tri-aryloxy-s-triazines were synthesized through the reaction of the corresponding phenols as a starting materials with cyanogen bromide (BrCN) to obtain the corresponding arylcyanates and then trimerized. Unexpectedly, 2,4-di-tert-butyl-1-cyanatobenzene derived from 2,4-di-tert-butylphenol did not trimerize but, indeed, yielded bis(2,4-di-tert-butylphenyl) carbonate. The structures of 2,4,6-tri-aryloxy-s-triazines and bis(2,4-di-tert-butylphenyl) carbonate were characterized by means of IR, 1H, and 13C NMR spectroscopies. Also the structure of the latter compound was studied by X-ray crystallography.

Nickel-Catalyzed Deoxycyanation of Activated Phenols via Cyanurate Intermediates with Zn(CN)2: A Route to Aryl Nitriles

A novel, and efficient nickel-catalyzed deoxycyanation of phenolic compounds using relatively nontoxic Zn(CN)2 as the cyanide source was developed. The reaction of C-O bond activated phenolic compounds by 2,4,6-trichloro-1,3,5-triazine with Zn(CN)2 in the presence of a nickel precatalyst afforded the aromatic nitriles in good to excellent yields.