117741-11-4

Basic information

• Product Name: 1-m-tolyl-1,2-dihydro-2-quinolone
• Synonyms: 1-m-tolyl-1,2-dihydro-2-quinolone
• CAS NO: 117741-11-4
• Molecular Weight: 235.285
• Mol File: 117741-11-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-m-tolyl-1,2-dihydro-2-quinolone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-m-tolyl-1,2-dihydro-2-quinolone(117741-11-4)
• EPA Substance Registry System: 1-m-tolyl-1,2-dihydro-2-quinolone(117741-11-4)

Safety Data

• Hazardous Substances Data: 117741-11-4(Hazardous Substances Data)

Upstream product

• 591-17-3 meta-bromotoluene 
• 5852-90-4 carbostyril; potassium-salt 
• 769968-22-1 (2E)-N-(3-methylphenyl)-3-phenylprop-2-enamide 

Relevant articles and documents

Visible-Light-Photocatalyzed Synthesis of Phenanthridinones and Quinolinones via Direct Oxidative C-H Amidation

A straightforward synthetic strategy to construct biologically relevant phenanthridinones and quinolinones was developed via visible-light-promoted direct oxidative C-H amidation. In this photocatalytic system, amidyl radicals can be generated by homolysis of the N-H bond of simple amide precursors via single-electron transfer under blue LED illumination, which leads to oxidative intramolecular C-H amidation. Moreover, an efficient synthetic strategy using a photocascade enabled facile assembly of quinolinone structures through a catalytic sequence involving triplet energy (ET) transfer-based E/Z olefin isomerization and subsequent photocatalytic generation of amidyl radical intermediates.