1181844-56-3

Basic information

• Product Name: 2,4-bis(bis(ethylthio)methylene)-3-(4-chlorophenyl)pentanedinitrile
• Synonyms: 2,4-bis(bis(ethylthio)methylene)-3-(4-chlorophenyl)pentanedinitrile
• CAS NO: 1181844-56-3
• Molecular Weight: 469.16
• Mol File: 1181844-56-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,4-bis(bis(ethylthio)methylene)-3-(4-chlorophenyl)pentanedinitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-bis(bis(ethylthio)methylene)-3-(4-chlorophenyl)pentanedinitrile(1181844-56-3)
• EPA Substance Registry System: 2,4-bis(bis(ethylthio)methylene)-3-(4-chlorophenyl)pentanedinitrile(1181844-56-3)

Safety Data

• Hazardous Substances Data: 1181844-56-3(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 91357-43-6 α-cyanoketene 3,5-dithiaheptane 

Relevant articles and documents

Copper(II)-catalyzed C-C bond-forming reactions of α-electron- withdrawing group-substituted ketene S,S-acetals with carbonyl compounds and a facile synthesis of coumarins

A new catalytic C-C bond-forming reaction has been developed. Catalyzed by cheap and commercially available copper(II) bromide (CuBr2; 10 mol%), the reactions of α-electron-withdrawing group (EWG)-substituted ketene S,S-acetals with aldehydes or ketones in acetonitrile at room temperature gave a variety of densely functionalized coupling products in excellent yields (80-98%). Based on this catalytic process, coumarin derivatives were efficiently synthesized when salicylaldehydes were selected as the carbonyl components.