118670-83-0

Basic information

• Product Name: Acetamide, N-(2-iodophenyl)-N-2-propenyl-
• CAS NO: 118670-83-0
• Molecular Formula: C11H12INO
• Molecular Weight: 301.127
• Mol File: 118670-83-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Acetamide, N-(2-iodophenyl)-N-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-(2-iodophenyl)-N-2-propenyl-(118670-83-0)
• EPA Substance Registry System: Acetamide, N-(2-iodophenyl)-N-2-propenyl-(118670-83-0)

Safety Data

• Hazardous Substances Data: 118670-83-0(Hazardous Substances Data)

Upstream product

• 19591-17-4 o-iodoacetanilide 
• 106-95-6 allyl bromide 
• 615-43-0 2-iodophenylamine 
• 75-36-5 acetyl chloride 

Downstream Products

• 681427-64-5 N-(2-ethynylphenyl)-N-(prop-1-enyl)acetamide 
• 55487-54-2 N-allyl-N-phenylacetamide 
• 4375-15-9 3-methyl-2,3-dihydro-1H-indole 
• 83-34-1 3-Methylindole 

Relevant articles and documents

Formal Bromine Atom Transfer Radical Addition of Nonactivated Bromoalkanes Using Photoredox Gold Catalysis

Organic transformations mediated by photoredox catalysis have been at the forefront of reaction discovery. Recently, it has been demonstrated that binuclear Au(I) bisphosphine complexes, such as [Au2(μ-dppm)2]X2, are capable of mediating electron transfer to nonactivated bromoalkanes for the generation of a variety of alkyl radicals. The transfer reactions of bromine, derived from nonactivated bromoalkanes, are largely unknown. Therefore, we propose that unique metal-based mechanistic pathways are at play, as this binuclear gold catalyst has been known to produce Au(III) Lewis acid intermediates. The scope and proposed mechanistic overview for the formal bromine atom transfer reaction of nonactivated bromoalkanes mediated by photoredox Au(I) catalysis is presented. The methodology presented afforded good yields and a broad scope which include examples using bromoalkanes and iodoarenes.

Enantioselective Intramolecular C?H Insertion of Donor and Donor/Donor Carbenes by a Nondiazo Approach

The first enantioselective intramolecular C?H insertion and cyclopropanation reactions of donor- and donor/donor-carbenes by a nondiazo approach are reported. The reactions were conducted in a one-pot manner without slow addition and provided the desired

Indole and quinoline synthesis via intramolecular Pauson-Khand reactions of enamines and allylamines

Syntheses of indoles and quinolines based upon the Pauson-Khand reaction is described. The starting materials are an aromatic ethynylenamine and ethynylallylamine, which are obtained via Sonogashira coupling. Also, an aromatic ynamine is used for an attem