118806-82-9Relevant articles and documents
Origin of stereocontrol in guanidine-bisurea bifunctional organocatalyst that promotes α-hydroxylation of tetralone-derived β-ketoesters: Asymmetric synthesis of β- And γ-substituted tetralone derivatives via organocatalytic oxidative kinetic resolution
Odagi, Minami,Furukori, Kota,Yamamoto, Yoshiharu,Sato, Makoto,Iida, Keisuke,Yamanaka, Masahiro,Nagasawa, Kazuo
supporting information, p. 1909 - 1915 (2015/03/04)
The mechanism of asymmetric α-hydroxylation of tetralone-derived β-ketoesters with guanidine-bisurea bifunctional organocatalyst in the presence of cumene hydroperoxide (CHP) was examined by means of DFT calculations to understand the origin of the stereo