1195901-22-4

Basic information

• Product Name: diphenyl-(1,3,5-trimethyl-1H-pyrazol-4-yl)-amine
• Synonyms: diphenyl-(1,3,5-trimethyl-1H-pyrazol-4-yl)-amine
• CAS NO: 1195901-22-4
• Molecular Weight: 277.369
• Mol File: 1195901-22-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: diphenyl-(1,3,5-trimethyl-1H-pyrazol-4-yl)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: diphenyl-(1,3,5-trimethyl-1H-pyrazol-4-yl)-amine(1195901-22-4)
• EPA Substance Registry System: diphenyl-(1,3,5-trimethyl-1H-pyrazol-4-yl)-amine(1195901-22-4)

Safety Data

• Hazardous Substances Data: 1195901-22-4(Hazardous Substances Data)

Upstream product

• 15801-69-1 4-bromo-1,3,5-trimethylpyrazole 
• 5856-89-3 lithium diphenylamide 

Relevant articles and documents

Oxidative amination of heteroaromatic zinc reagents mediated by PhI(OAc)2

The oxidative amination of functionalized heterocycles has been achieved by using readily available heterocyclic zinc reagents and lithium amides. PhI(OAc)2 proved to be a suitable reagent for this oxidative amination

Preparation of heterocyclic amines via a copper(i)-mediated oxidative cross-coupling of organozinc reagents with lithium amides

Functionalized heteroaromatic amines are readily prepared by the oxidative coupling of polyfunctional zinc amidocuprates using PhI(OAc)2 as oxidant. Various sensitive heterocyclic organometallics undergo this oxidative cross-coupling reaction furnishing aminated heteroaromatics. A high functional group tolerance and relative insensibility to steric hindrance characterize this general amination reaction. A practical procedure for the preparation of protected primary and secondary as well as tertiary heteroaryl amines is described. Georg Thieme Verlag Stuttgart - New York.