1198151-79-9

Basic information

• Product Name: (N,N,N',N',-tetramethyl)diamidothiophophosphoric acid O-(3-diphenylthiophosphoryl)phenyl ester
• CAS NO: 1198151-79-9
• Molecular Weight: 460.541
• Mol File: 1198151-79-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (N,N,N',N',-tetramethyl)diamidothiophophosphoric acid O-(3-diphenylthiophosphoryl)phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (N,N,N',N',-tetramethyl)diamidothiophophosphoric acid O-(3-diphenylthiophosphoryl)phenyl ester(1198151-79-9)
• EPA Substance Registry System: (N,N,N',N',-tetramethyl)diamidothiophophosphoric acid O-(3-diphenylthiophosphoryl)phenyl ester(1198151-79-9)

Safety Data

• Hazardous Substances Data: 1198151-79-9(Hazardous Substances Data)

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 32341-36-9 m-hydroxyphenyl(diphenyl)phosphine sulfide 
• 3732-81-8 N,N,N',N'-tetramethylphosphorodiamidothioic chloride 
• 13145-84-1 (3-methoxyphenyl)(diphenyl)phosphane 
• 2398-37-0 3-methoxyphenyl bromide 

Downstream Products

• 1198151-83-5 [2-([bis(dimethylamino)thiophosphoryl]oxy)-6-(diphenylthiophosphoryl)phenyl]-palladium chloride 

Relevant articles and documents

Thiophosphoryl-, thiophosphoryloxy-, and thiophosphorylamino-benzene derivatives as novel classes of hybrid pincer ligands

The synthetic approaches to novel families of SCE (E = S',N,O) hybrid pincertype ligands bearing thophosphoryl, thiophosphoryloxy, and thiophosphorylamino groups in various combinations with thiophosphoryl-, thiocarbamoyl-, and imine- (including that of benzothiazole ring) donating functions have been developed. All of the ligands readily undergo direct cyclometallation (metal = Pd(II), Pt(II)) to afford 5,5- or 5,6-membered pincer complexes. Palladium complexes displayed from high to excellent catalytic performance in the Suzuki cross-coupling reaction of aryl bromides and phenylboronic acid and the higher asymmetry for a complex served as a factor of its higher catalytic activity. Copyright Taylor & Francis Group, LLC.