120046-05-1

Basic information

• Product Name: 2-(α-hydroxybenzyl)-2-phenyl-1,3-dithiane
• Synonyms: 2-(α-hydroxybenzyl)-2-phenyl-1,3-dithiane
• CAS NO: 120046-05-1
• Molecular Weight: 302.461
• Mol File: 120046-05-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(α-hydroxybenzyl)-2-phenyl-1,3-dithiane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(α-hydroxybenzyl)-2-phenyl-1,3-dithiane(120046-05-1)
• EPA Substance Registry System: 2-(α-hydroxybenzyl)-2-phenyl-1,3-dithiane(120046-05-1)

Safety Data

• Hazardous Substances Data: 120046-05-1(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 5425-44-5 2-Phenyl-[1,3]dithiane 

Downstream Products

• 451-40-1 phenyl benzyl ketone 
• 119-53-9 2-hydroxy-2-phenylacetophenone 

Relevant articles and documents

HYDROLYSIS OF KETOL TRIMETHYLENEDITHIOACETALS. ATTEMPTED SYNTHESIS OF YASHABUSHIKETOL

Thallium(III) trifluoroacetate has been shown to cleave dithianes which contain hydroxy functions that other reagents fail.Hydrolysis of a direct precursor of yashabushiketol led to tetrahydro-γ-pyrones, however.

A convenient preparation of symmetrical and unsymmetrical 1,2-diketones: Application to fluorinated phenytoin synthesis

1,2-Diketones are efficiently produced in two steps by reaction of aldehydes with anions derived from 2-substituted dithianes followed by treatment of the resulting alcoholis with NBS in aqueous acetone; phenytoin derivatives were prepared from these diketones by a standard method involving treatment with urea and potassium hydroxide under reflux.