1203584-64-8

Basic information

• Product Name: tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranose
• Synonyms: tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranose
• CAS NO: 1203584-64-8
• Molecular Weight: 728.849
• Mol File: 1203584-64-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranose(1203584-64-8)
• EPA Substance Registry System: tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranose(1203584-64-8)

Safety Data

• Hazardous Substances Data: 1203584-64-8(Hazardous Substances Data)

Upstream product

• 129729-40-4 3,4,6-tri-O-acetyl-2-deoxy-2-p-methoxybenzylideneamino-D-glucopyranose 
• 1203584-54-6 1-O-tert-butyldiphenylsilyl-3,4,6-tri-O-acetyl-2-deoxy-2-amino-β-D-glucopyranoside 
• 98-74-8 4-Nitrobenzenesulfonyl chloride 
• 1203584-53-5 tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose 
• 114297-26-6 1,3,4,6-tetra-O-acetyl-2-deoxy-2-{[(4-methoxyphenyl)methylidene]amino}-D-glucopyranose 

Downstream Products

• 1203584-66-0 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate 
• 1203584-56-8 methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside 

Relevant articles and documents

Synthesis of differentially protected glucosamine building blocks and their evaluation as glycosylating agents

The modular assembly of heparin oligosaccharides requires glucosamine building blocks with amine protecting groups for α-selective glycosylations that can be readily removed. The synthesis of N-4-nitrobenzensulphonamide (nosyl)- and N-2,4-dinitrophenyl (DNP)-protected glucosamine building blocks and their evaluation as glycosylating agents is described. The N-nosyl-protected glucosamine building blocks were challenging to prepare and their glycosylations resulted in inseparable mixtures of products. The N-DNP-protected glucosamines, however, were readily synthesized and resulted in α-selective couplings to protected l-iduronic acid derivatives.