120693-89-2

Basic information

• Product Name: (E,4'R,5'S,6'S)-(+)-methyl 3-5'-benzyloxy-6'-benzyloxymethyl-1',3'-dioxan-4'-yl-acrylate
• CAS NO: 120693-89-2
• Molecular Weight: 398.456
• Mol File: 120693-89-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E,4'R,5'S,6'S)-(+)-methyl 3-5'-benzyloxy-6'-benzyloxymethyl-1',3'-dioxan-4'-yl-acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (E,4'R,5'S,6'S)-(+)-methyl 3-5'-benzyloxy-6'-benzyloxymethyl-1',3'-dioxan-4'-yl-acrylate(120693-89-2)
• EPA Substance Registry System: (E,4'R,5'S,6'S)-(+)-methyl 3-5'-benzyloxy-6'-benzyloxymethyl-1',3'-dioxan-4'-yl-acrylate(120693-89-2)

Safety Data

• Hazardous Substances Data: 120693-89-2(Hazardous Substances Data)

Upstream product

• 109-87-5 Dimethoxymethane 
• 102487-47-8 (E)-(4R,5S,6S)-5,7-Bis-benzyloxy-4,6-dihydroxy-hept-2-enoic acid methyl ester 
• 102487-47-8 (E,4S,5R,6R)-methyl 5,7-di(benzyloxy)-4,6-dihydroxy-2-heptenoate 
• 131156-47-3 (3aS,3bR,7aS,8aS)-2,2,5,5-tetramethyltetrahydro-3aH-[1,3]dioxolo[4',5':4,5]furo[3,2-d][1,3]dioxane 
• 114861-22-2 1,2-O-isopropylidene-α-L-xylofuranose 
• 87-72-9 L-(-)-xylose 
• 16054-77-6 3,5-di-O-benzyl-L-xylofuranose 
• 20881-04-3 1,2:3,5-di-O-isopropylidene-D-xylofuranose 
• 87-72-9 D-(+)-xylose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 100-44-7 benzyl chloride 
• 16054-77-6 3,5-di-O-benzyl-D-xylofuranose 
• 41341-99-5 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 50-00-0 formaldehyd 

Downstream Products

• 113473-80-6 4-((4S,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-[1,3]dioxan-4-yl)-piperidine-2,6-dione 
• 85719-78-4 (+)-sesbanimide A 
• 102487-50-3 3-((4S,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-[1,3]dioxan-4-yl)-4-carbamoyl-butyric acid 
• 102487-49-0 3-((4S,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-[1,3]dioxan-4-yl)-pentanedioic acid 
• 108926-38-1 4-{(4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[3-(tert-butyl-diphenyl-silanyloxymethyl)-1-hydroxy-2-methyl-but-3-enyl]-[1,3]dioxan-4-yl}-piperidine-2,6-dione 
• 85719-78-4 (-)-sesbanimide B 
• 102487-44-5 (4'S,5'R,6'R)-(+)-4-5'-benzyloxy-6'-benzyloxymethyl-1',3'-dioxan-4'-yl-2,6-piperidinedione 
• 102487-48-9 (4'S,5'R,6'R)-(-)-dimethyl 3-5'-benzyloxy-6'-benzyloxymethyl-1',3'-dioxan-4'-yl-glutarate 
• 102487-48-9 3-((4R,5S,6S)-5-Benzyloxy-6-benzyloxymethyl-[1,3]dioxan-4-yl)-pentanedioic acid dimethyl ester 
• 102487-49-0 3-((4R,5S,6S)-5-Benzyloxy-6-benzyloxymethyl-[1,3]dioxan-4-yl)-pentanedioic acid 
• 102487-50-3 3-((4R,5S,6S)-5-Benzyloxy-6-benzyloxymethyl-[1,3]dioxan-4-yl)-4-carbamoyl-butyric acid 
• 120786-90-5 4-((4R,5S,6S)-5-Benzyloxy-6-benzyloxymethyl-[1,3]dioxan-4-yl)-piperidine-2,6-dione 
• 126267-16-1 (1R,2S,6R,7R,9S)-(+)-9-(tert-butyldiphenylsilyloxy)-6-<(1S,2R)-1-hydroxy-2-methyl-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2.7>tridecan-11-one 
• 126267-16-1 (1R,2S,6R,7R,9S)-(-)-9-(tert-butyldiphenylsilyloxy)-6-<(1R,2S)-1-hydroxy-2-methyl-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2.7>tridecan-11-one 

Relevant articles and documents

EFFICIENT SYNTHESIS AND ANTITUMOR ACTIVITY OF AN ENANTIOMERIC PAIR OF THE SESBANIMIDE AB-RING SYSTEMS

An enantiomeric pair of the fully unprotected AB-ring systems of sesbanimide A (1), a potent antitumor alkaloid, was efficiently synthesized from readily available D- and L-xylose.Examination on their in vitro antitumor activity clearly disclosed that the AB-ring system only made a small contribution to the notable cytotoxicity of 1.

Total synthesis of natural (+)-sesbanimide A and (-)-sesbanimide B

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