1214888-23-9

Basic information

• Product Name: N-(2-(allyldimethylsilyloxy)pent-4-enyl)-4-methylbenzenesulfonamide
• Synonyms: N-(2-(allyldimethylsilyloxy)pent-4-enyl)-4-methylbenzenesulfonamide
• CAS NO: 1214888-23-9
• Molecular Weight: 353.558
• Mol File: 1214888-23-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2-(allyldimethylsilyloxy)pent-4-enyl)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-(allyldimethylsilyloxy)pent-4-enyl)-4-methylbenzenesulfonamide(1214888-23-9)
• EPA Substance Registry System: N-(2-(allyldimethylsilyloxy)pent-4-enyl)-4-methylbenzenesulfonamide(1214888-23-9)

Safety Data

• Hazardous Substances Data: 1214888-23-9(Hazardous Substances Data)

Upstream product

• 4028-23-3 Allylchlorodimethylsilane 
• 1214887-93-0 N-(2-hydroxypent-4-enyl)-4-methylbenzenesulfonamide 

Downstream Products

• 1214888-00-2 (Z)-N-(2-hydroxy-6-(trimethylsilyl)hex-4-enyl)-4-methylbenzenesulfonamide 

Relevant articles and documents

New modes for the osmium-catalyzed oxidative cyclization

(Figure Presented) The osmium-catalyzed oxidative cyclization of amino alcohol initiators formally derived from 1,4-dienes Is an effective method for the construction of pyrrolidines, utilizing a novel reoxidant (4-nltropyridlne N-oxide = NPNO). The cyclization of enantlopure syn- and anti-amino alcohols gives rise to enantlopure cis- and frans-2,5-disubstituted pyrrolidines, respectively. Moreover, the cyclization of Ws-homoallylic amines bearing an exocyclic chelating group Is shown to be a complementary method for irans-pyrrolidine formation.