1220392-97-1Relevant articles and documents
Synthesis of 2-Arylamino-1,3,5-triazines from 2-Aminotriazines with Aryl Halides via CuI-Catalyzed Ullmann Coupling Reaction
Li, Jin Jing,Wu, Kong,Zhou, Wei,Wang, Hong,Cui, Dong-Mei,Zhang, Chen
, p. 1993 - 1996 (2016)
An efficient copper-catalyzed synthesis of 2-arylamino-1,3,5-triazines from 2-aminotriazines with aryl halides under mild conditions has been developed. The reaction occurred in moderate to good yields and tolerated aryl iodides containing functionalities
Asymmetrically substituted 1, 3, 5-triazine compound as well as preparation method and application thereof
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Paragraph 0085-0091; 0295-0302; 0313-0330, (2020/09/12)
The invention relates to the technical field of biocatalytic synthesis, and particularly discloses an asymmetrically substituted 1, 3, 5-triazine compound as well as a preparation method and application thereof. The asymmetrically substituted 1, 3, 5-triazine compound comprises the following raw materials: an isothiocyanate compound, an amidine compound and tetramethylguanidine. According to the asymmetrically substituted 1, 3, 5-triazine compound, heme, horse radish peroxidase, hemoglobin or cytochrome C is adopted as a catalyst, so that the asymmetrically substituted 1, 3, 5-triazine compound is green, non-toxic, environmentally friendly and high in yield, and the problem that most of existing asymmetrically substituted 1, 3, 5-triazine compounds adopt toxic catalysts in preparation, arenot environmentally friendly and are low in yield is solved; and the preparation method provided by the invention is superior to the traditional chemical synthesis method, has the advantages of highefficiency, greenness, short reaction time, mild reaction conditions and no difficult-to-treat metal ion catalysis, and lowers the catalyst consumption.
Method for preparing asymmetric poly-substituted amino-1,3,5-triazine compound by photocatalysis
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Paragraph 0065-0072, (2019/10/23)
The invention provides a method for preparing an asymmetric poly-substituted amino-1,3,5-triazine compound by photocatalysis and relates to the technical field of organic intermediate synthesis. According to the method, an amidine compound, an isothiocyan