122090-90-8

Basic information

• Product Name: (3R,4S)-4-hydroxy-3-methylcyclohexanone
• Synonyms: (3R,4S)-4-hydroxy-3-methylcyclohexanone
• CAS NO: 122090-90-8
• Molecular Weight: 128.171
• Mol File: 122090-90-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4S)-4-hydroxy-3-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4S)-4-hydroxy-3-methylcyclohexanone(122090-90-8)
• EPA Substance Registry System: (3R,4S)-4-hydroxy-3-methylcyclohexanone(122090-90-8)

Safety Data

• Hazardous Substances Data: 122090-90-8(Hazardous Substances Data)

Upstream product

• 96894-00-7 (1S,2S)-4,4-ethylenedioxy-2-hydroxymethylcyclohexanol 
• 96893-99-1 (1R,2S)-5,5-(Ethylendioxy)-2-hydroxycyclohexancarbonsaeure-ethylester 
• 96817-54-8 ethyl (1R,2S)-2-acetoxy-5,5-ethylenedioxycyclohexanecarboxylate 
• 122052-59-9 (1S,2R)-2-bromomethyl-4,4-ethylenedioxycyclohexyl benzoate 
• 122052-44-2 (2R,4aS,8aS)-6,6-ethylenedioxy-2-phenyl-1,3-dioxa-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene 
• 122090-89-5 (1S,2R)-4,4-ethylenedioxy-2-methylcyclohexanol 
• 14160-65-7 ethyl 8-oxo-1,4-dioxaspiro[4.5]decane-7-carboxylate 

Downstream Products

• 122090-96-4 3-[(1R,2R,3R)-1,2-Dimethyl-6-oxo-3-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-propionic acid methyl ester 
• 122052-43-1 3-[(1R,2R,3S)-1,2-Dimethyl-6-oxo-3-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-propionic acid methyl ester 
• 122090-97-5 3-[(1R,2R,3R)-1,2-Dimethyl-6-oxo-3-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-propionic acid 
• 122090-91-9 (1'R,2'R,3'S)-3-(1',2'-dimethyl-6'-oxo-3'-tetrahydropyranyloxycyclohexane)propanoic acid 
• 122090-95-3 3-((6R,7R,8S)-8-Hydroxy-6,7-dimethyl-1,4-dioxa-spiro[4.5]dec-6-yl)-propionic acid 
• 122052-46-4 (1'R,2'R,3'R)-3-(6',6'-ethylenedioxy-3'-hydroxy-1',2'-dimethylcyclohexane)propanoic acid 
• 111210-55-0 3-[(1R,5S,6R)-3-[1-Benzylsulfanyl-meth-(E)-ylidene]-1,6-dimethyl-2-oxo-5-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-propionic acid ethyl ester 
• 122169-37-3 (2RS,3R,4S)-6-benzylthiomethylene-2,3-dimethyl-4-tetrahydropyranyloxycyclohexanone 
• 122052-63-5 benzyl (1'R,2'R)-3-(6',6'-ethylenedioxy-1',2'-dimethyl-3'-oxocyclohexane)propanoate 
• 122052-45-3 benzyl (1'R,2'R,3'S)-3-(6',6'-ethylenedioxy-3'-hydroxy-1',2'-dimethylcyclohexane)propanoate 
• 122052-64-6 3-((1R,2R,3R)-3-Hydroxy-1,2-dimethyl-6-oxo-cyclohexyl)-propionic acid methyl ester 
• 122052-60-2 (3R,4S)-3-methyl-4-tetrahydropyranyloxycyclohexanone 

Relevant articles and documents

EFFICIENT SYNTHESIS OF NATURAL ENANTIOMER OF SPOROGEN-AO 1 (13-DESOXYPHOMENONE), A SPOROGENIC SESQUITERPENE FROM ASPERGILLUS ORYZAE

An efficient total synthesis of (+)-sporogen-AO 1 (13-desoxyphomenone) 1 was achieved in 20 steps from ethyl (1R,2S)-5,5-ethylenedioxy-2-hydroxycyclohexanecarboxylate 3 in 8.3percent overall yield.The optically active 3 with 98.4percent e.e. was easily ob