1227099-28-6

Basic information

• Product Name: [Pd(SC₆F₄-4-H)2(TMEDA)]
• CAS NO: 1227099-28-6
• Molecular Weight: 584.894
• Mol File: 1227099-28-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(SC₆F₄-4-H)2(TMEDA)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(SC₆F₄-4-H)2(TMEDA)](1227099-28-6)
• EPA Substance Registry System: [Pd(SC₆F₄-4-H)2(TMEDA)](1227099-28-6)

Safety Data

• Hazardous Substances Data: 1227099-28-6(Hazardous Substances Data)

Upstream product

• 14267-08-4 N,N,N',N'-tetramethylethylenediamine palladium(II) chloride 
• 110-18-9 N,N,N,N,-tetramethylethylenediamine 

Relevant articles and documents

Synthesis and characterization of sterically hindered thiolate Pd(II) complexes of the type [Pd(SR)2(TMEDA)]: Examination of their catalytic properties in phosphane-free Suzuki-Miyaura cross couplings

The sterically hindered thiolate complexes [Pd(SR)2(TMEDA)] SR = SC6F5 (2), SC6F4-4-H (3), SC6H4-2-SiPh3 (4) were easily synthesized by metathetical reactions of the corresponding palladium chloro compound [Pd(Cl)2(TMEDA)] (1) and the lead salt of the corresponding thiol. The identity of the three species being unequivocally determined by single crystal X-ray diffraction techniques. The catalytic activity of the palladium species [Pd(SR)2(TMEDA)] was explored in the Suzuki-Miyaura cross coupling reactions of different p-substituted bromobenzenes.