122752-74-3

Basic information

• Product Name: 2-Butanone, 4-(2-iodophenyl)-
• CAS NO: 122752-74-3
• Molecular Formula: C10H11IO
• Molecular Weight: 274.101
• Mol File: 122752-74-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 4-(2-iodophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 4-(2-iodophenyl)-(122752-74-3)
• EPA Substance Registry System: 2-Butanone, 4-(2-iodophenyl)-(122752-74-3)

Safety Data

• Hazardous Substances Data: 122752-74-3(Hazardous Substances Data)

Upstream product

• 59473-45-9 2-(chloromethyl)iodobenzene 
• 123-54-6 acetylacetone 
• 40400-13-3 2-Iodobenzyl bromide 
• 141-97-9 ethyl acetoacetate 
• 96606-95-0 3-(2-iodophenyl)propanoic acid 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 22720-75-8 2-acetyl benzo[b]thiophene 
• 501346-75-4 trans-[Pd(triphenylphosphine)2(C₆H₄(CH₂)2C(O)CH₃)I] 

Relevant articles and documents

Nickel-Catalyzed Reductive Arylalkylation via a Migratory Insertion/Decarboxylative Cross-Coupling Cascade

Reported is a nickel-catalyzed reductive arylalkylation of unactivated alkenes tethered to aryl iodides with redox active N-hydroxyphthalimide esters as the alkyl source through successful merging of migratory insertion and decarboxylative cross-coupling in a cascade. This new method avoids the use of pregenerated organometallic reagents and thus enables the synthesis of diverse benzene-fused carbo- and heterocyclic compounds with high tolerance of a wide range of functional groups.

Copper-catalyzed synthesis of 2-acylbenzo[: B] thiophenes from 3-(2-iodophenyl)-1-arylpropan-1-ones and potassium sulfide under aerobic conditions

A method was developed for the synthesis of 2-acylbenzo[b]thiophenes via a copper-catalyzed sulfuration of 3-(2-iodophenyl)-1-arylpropan-1-ones with K2S under aerobic conditions. Mechanistically, this procedure was proved to involve the formati

ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

Compounds having the structure of Formula M(LA)x(LB)y and Formula III, are disclosed. In Formula M(LA)x(LB)y, Ligand LA is and ligand LB is a mono anionic bidentate ligand. In these compounds, metal M has an atomic number greater than 40; x is 1, 2, or 3; y is 0, 1, or 2; x+y is the oxidation state of metal M; L11 represents a linking group selected from alkyl, cycloalkyl, aryl, and heteroaryl; L12 represents a linking group selected from NR15 and PR15; each R1, R2, R3, R4, R5, R6, R11, R12, R13, R14, and R15 is independently selected from a group of substituents, wherein any adjacent substituents are optionally joined to form a fused or unfused ring; and LA and LB are optionally joined to form a ligand that is at least tetradentate. Formulations and devices, such as OLEDs, that include the compound of Formula M(LA)x(LB)y are also described.