122865-80-9

Basic information

• Product Name: C₂₁H₁₇⁽²⁾HO₅PS^(1-)*Na⁽¹⁺⁾
• CAS NO: 122865-80-9
• Molecular Weight: 437.393
• Mol File: 122865-80-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₁H₁₇⁽²⁾HO₅PS^(1-)*Na⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₁H₁₇⁽²⁾HO₅PS^(1-)*Na⁽¹⁺⁾(122865-80-9)
• EPA Substance Registry System: C₂₁H₁₇⁽²⁾HO₅PS^(1-)*Na⁽¹⁺⁾(122865-80-9)

Safety Data

• Hazardous Substances Data: 122865-80-9(Hazardous Substances Data)

Upstream product

• 63995-75-5 sodium 3-(diphenylphosphanyl)benzenesulfonate 
• 79-10-7 acrylic acid 

Relevant articles and documents

Organic Chemistry in water (part II). NUCLEOPHILIC ADDITION OF WATER-SOLUBLE PHOSPHINES ON ACTIVATED OLEFINS

Triphenylphosphine m-trisulfonate P(PhSO3Na)3 = TPPTS and triphenylphosphine m-monosulfonate Ph2PPhSO3Na = TPPMS react in water with α,β unsaturated acids affording hydrosoluble phosphonium salts.The conversion is quantitative because water readily protonates the carbanionic intermediate thus displacing the equilibrum towards the right.This nucleophilic addition of hydrosoluble phosphines has been extended to non water miscible activated olefins in biphasic media; depending on the pH, phosphine oxides or phosphonium salts are obtained.When the reactions are carried out in D2O, the addition products are specifically deuterated.