1232774-87-6

Basic information

• Product Name: 1,1-bis(dimethylamino)-N,N-dimethyl-N'-phenylphosphinecarboximidamide
• Synonyms: 1,1-bis(dimethylamino)-N,N-dimethyl-N'-phenylphosphinecarboximidamide
• CAS NO: 1232774-87-6
• Molecular Weight: 266.326
• Mol File: 1232774-87-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,1-bis(dimethylamino)-N,N-dimethyl-N'-phenylphosphinecarboximidamide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-bis(dimethylamino)-N,N-dimethyl-N'-phenylphosphinecarboximidamide(1232774-87-6)
• EPA Substance Registry System: 1,1-bis(dimethylamino)-N,N-dimethyl-N'-phenylphosphinecarboximidamide(1232774-87-6)

Safety Data

• Hazardous Substances Data: 1232774-87-6(Hazardous Substances Data)

Upstream product

• 124-40-3 dimethyl amine 
• 1783-25-1 N₁,N₁-dimethyl-N₂-phenylformamidine 
• 1232774-70-7 1,1-bis(dimethylamino)-N,N-dimethyl-N'-phenylphosphinecarboximidamide selenide 

Downstream Products

• 1232774-70-7 1,1-bis(dimethylamino)-N,N-dimethyl-N'-phenylphosphinecarboximidamide selenide 

Relevant articles and documents

Zwitterionic Phosphoranides as Intermediates in the Reaction of Phosphorus Tribromide with N,N-Dimethyl-N′-arylformamidines

Cyclic zwitterionic phosphoranides 2a,b were found to be intermediate products in the reaction of N,N-dimethyl-N′-(aryl)formamidines with PBr3. The structure of phosphoranide 2a was determined by means of the X-ray and quantum chemistry investigations. Mechanism of its formation was proposed based on Density functional theory (DFT) calculations. Reactions of 2 with amines and selenium yielded either C-phosphorylated formamidines or benzazaphospholes. The first example of intramolecular heterocyclization of a pentavalent phosphorus derivative 15b into 3Cyrillic capital letter en-1,3-benzazaphosphole has been demonstrated.