123312-23-2

Basic information

• Product Name: Benzene, 1-methoxy-3-(2-nitroethyl)-
• CAS NO: 123312-23-2
• Molecular Formula: C9H11NO3
• Molecular Weight: 181.191
• Mol File: 123312-23-2.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-3-(2-nitroethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-3-(2-nitroethyl)-(123312-23-2)
• EPA Substance Registry System: Benzene, 1-methoxy-3-(2-nitroethyl)-(123312-23-2)

Safety Data

• Hazardous Substances Data: 123312-23-2(Hazardous Substances Data)

Upstream product

• 75-52-5 nitromethane 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 152356-73-5 (Z)-1-(3-methoxyphenyl)-2-nitroethene 
• 3179-09-7 (E)-1-methoxy-3-(2-nitrovinyl)benzene 
• 3179-09-7 1-methoxy-3-(2-nitrovinyl)benzene 

Downstream Products

• 152356-74-6 tert-butyl 5-(3-methoxyphenyl)-4-nitrovalerate 
• 1255037-14-9 3-(3-methoxyphenyl)-2-nitropropan-1-ol 
• 123312-30-1 2-(2-Bromo-5-methoxy-phenyl)-N-[2-(3-methoxy-phenyl)-butyl]-acetamide 
• 123312-35-6 1-(2-Bromo-5-methoxy-benzyl)-4-ethyl-6-methoxy-1,2,3,4-tetrahydro-isoquinoline 
• 123312-25-4 2-(3-methoxyphenyl)-1-butanamine 
• 123312-24-3 1-methoxy-3-[1-(nitromethyl)propyl]benzene 

Relevant articles and documents

Reduction of α,β-unsaturated nitroolefins into nitroalkanes with Hantzsch ester promoted by isothiouronium salts

α,β-Unsaturated nitroolefins were reduced into nitroalkanes with a Hantzsch ester, promoted by S-benzyl isothiouronium iodide. The reactions proceeded successfully to afford the desired products in high yields and with excellent chemoselectivity.

The highly chemoselective transfer hydrogenation of the carbon-carbon double bond of conjugated nitroalkenes by a rhodium complex

Chemoselective transfer hydrogenation of conjugated nitroalkenes catalyzed by [RhCl2Cp·]2-diamine complex (Cp ·=η5-C5Me5) using HCOOH/Et3N (5:2) (TEAF) as a hydrogen source was realized. A variety of nitrostyrenes, β-methyl nitrostyrenes, and 3-methyl-4-nitro-5-alkenyl- isoxazoles were reduced smoothly in good to excellent yields in short reaction time. Other functional groups are inert under the reaction conditions.

Ethanolamine derivatives having sympathomimetic and anti-pollakiuria activities

This invention relates to new ethanolamine derivatives having gut selective sympathomimetic and anti-pollakiuria activities and represented by the general formula [I]: STR1 wherein R1 is aryl or a heterocyclic group, each of which may be substituted with halogen, etc., R2 is hydrogen, halogen, nitro, hydroxy, lower alkyl optionally substituted with acyl, lower alkenyl optionally substituted with acyl, lower alkoxy optionally substituted with acyl, or amino optionally substituted with acyl(lower)alkyl, R3 is hydrogen, an N-protective group, or lower alkyl optionally substituted with lower alkylthio, n is an integer of 0 to 3, and a heavy solid line means a single bond or a double bond, provided that when n is 1, then 1) R1 is a condensed aromatic hydrocarbon group or a heterocyclic group, each of which may be substituted with halogen, etc., and the like, and pharmaceutically acceptable salts thereof to processes for the preparation thereof and to a pharmaceutical composition comprising the same.