123335-02-4

Basic information

• Product Name: Benzenemethanol, 2-bromo-a-(2-bromophenyl)-
• CAS NO: 123335-02-4
• Molecular Formula: C13H10Br2O
• Molecular Weight: 342.03
• Mol File: 123335-02-4.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-bromo-a-(2-bromophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-bromo-a-(2-bromophenyl)-(123335-02-4)
• EPA Substance Registry System: Benzenemethanol, 2-bromo-a-(2-bromophenyl)-(123335-02-4)

Safety Data

• Hazardous Substances Data: 123335-02-4(Hazardous Substances Data)

Upstream product

• 583-55-1 1-Bromo-2-iodobenzene 
• 6630-33-7 ortho-bromobenzaldehyde 
• 583-53-9 2,3-dibromobenzene 
• 25187-01-3 2,2’-dibromobenzophenone 
• 109-94-4 formic acid ethyl ester 
• 107-31-3 Methyl formate 
• 61592-98-1 1,2-bis(2-bromophenyl)-2-hydroxyethan-1-one 

Downstream Products

• 59142-47-1 (2-bromophenyl)phenylmethanol 
• 1184184-87-9 C₁₃H₁₀⁽²⁾HBrO 
• 91-01-0 1,1-Diphenylmethanol 
• 245432-28-4 (R)-(2-bromophenyl)(phenyl)methanol 
• 143880-86-8 (S)-o-bromobenzhydrol 
• 42196-97-4 9-trans-styryl-anthracene 
• 713542-04-2 1,3,5-tri(anthracen-9-yl)benzene 

Relevant articles and documents

Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

Construction of Various Bridged Polycyclic Skeletons by Palladium-Catalyzed Dearomatization

A powerful palladium-catalyzed dearomative cyclization was developed that provides facile access to eight types of bridged tetracyclic skeletons bearing various ring sizes and heterocycles. With this method, several skeletons or analogues of natural products, including tubingensin B and dracaenones, were synthesized. Asymmetric dearomative cyclization enables the construction of various enantiomerically enriched bridged polycyclic systems with up to 99 % ee by employing a chiral palladium catalyst.

Method for functionalizing o-dihalogenated aromatic hydrocarbon compound

The invention provides a method for functionalizing an o-dihalogenated aromatic hydrocarbon compound, which comprises the following steps: dissolving the o-dihalogenated aromatic hydrocarbon compoundin an organic solvent, controlling the temperature of th

Copper-Catalyzed N,N-Diarylation of Amides for the Construction of 9,10-Dihydroacridine Structure and Applications in the Synthesis of Diverse Nitrogen-Embedded Polyacenes

We reported herein CuI/DMEDA catalyzed N,N-diarylation reaction of amides with various di(o-bromoaryl)methanes to produce diverse 9,10-dihydroacridine derivatives. The resulting 9,10-dihydroacridine derivatives were oxidized selectively under mild conditions to afford acridine, acridinone, and acridinium derivatives. The copper-catalyzed N,N-diarylation reaction coupled with oxidative aromatization reaction enabled the facile construction of nitrogen atom-embedded tetracenes and pentacenes of different ortho-fused patterns. The luminescence properties, especially the effect of fusion pattern on fluorescence emission of acquired N-polycenes, were also demonstrated.