1233704-34-1

Basic information

• Product Name: [RhCl(CO)(C₈H₆O(C₆H₅)2)]2
• Synonyms: [RhCl(CO)(C₈H₆O(C₆H₅)2)]2
• CAS NO: 1233704-34-1
• Molecular Weight: 877.431
• Mol File: 1233704-34-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RhCl(CO)(C₈H₆O(C₆H₅)2)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [RhCl(CO)(C₈H₆O(C₆H₅)2)]2(1233704-34-1)
• EPA Substance Registry System: [RhCl(CO)(C₈H₆O(C₆H₅)2)]2(1233704-34-1)

Safety Data

• Hazardous Substances Data: 1233704-34-1(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 49769-17-7 1,7-diphenylhepta-1,6-diyne 

Downstream Products

• 1233704-37-4 [RhCl(NC₅H₅)2(C₈H₆O(C₆H₅)2)] 
• 15318-33-9 trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) 

Relevant articles and documents

Synthesis of [RhCl(CO)(cyclopentadienone)]2 from [RhCl(cod)]2 and a 1,6-diyne under CO: Application to Rh(i)-catalyzed tandem [2+2+1] carbonylative cycloaddition of diynes and Claisen rearrangement

Although Rh(i)Cl(CO)(cpd) (cpd = cyclopentadienone) complexes were identified more than 40 years ago, their exact structures have not been determined because of the polymeric nature of these complexes. We determined the structure of [Rh(i)Cl(CO)(cpd)]2, which was formed by the reaction of [Rh(cod)Cl]2 with a 1,6-diyne under CO. In addition, based on determination of the structure of the [Rh(i)Cl(CO)(cpd)]2 complex, we identified a new catalytic tandem reaction - the Rh-catalyzed [2+2+1] carbonylative cycloaddition of phenoxide-substituted diynes and Claisen rearrangement.