123457-65-8Relevant articles and documents
IMPROVED SYNTHESES OF TWO 3-DEOXYALD-2-ULOSONIC ACIDS(KDN,KDO) BY CONDENSATION OF OXALACETIC ACID WITH ALDOSES FOLLOWED BY Ni2+CATALYZED DECARBOXYLATION
Shirai, Ryuichi,Ogura, Haruo
, p. 2263 - 2264 (1989)
Condensation of oxalacetic acid with D-mannose and D-arabinose followed by Ni2+catalyzed decarboxylation gave 3-deoxy-D-glycero-D-galacto-2-nonulosonic acid(KDN) and 3-deoxy-D-manno-2-octulosonic acid(KDO) respectively in high chemical yield and high diastereoselectivity.