123536-32-3

Basic information

• Product Name: 6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one
• Synonyms: 6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one
• CAS NO: 123536-32-3
• Molecular Weight: 217.062
• Mol File: 123536-32-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one(123536-32-3)
• EPA Substance Registry System: 6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one(123536-32-3)

Safety Data

• Hazardous Substances Data: 123536-32-3(Hazardous Substances Data)

Upstream product

• 934-30-5 5-norbornene-endo-2-carboxylic acid 
• 263713-64-0 2,6,6-trimethyl-5,5-bis(trimethylsilyl)-5,6-disilaheptan-2-ol 
• 120-74-1 (1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 
• 120-74-1 5-carboxybicyclo<2.2.1>hept-2-ene 

Downstream Products

• 286456-64-2 (1S,3R,6S,7R)-5-Oxo-4-aza-tricyclo[4.2.1.0^3,7]nonane-3-carboxylic acid 
• 120-74-1 (1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 
• 58001-99-3 5-norbornene-2-carboxylic acid 

Relevant articles and documents

Indole-Catalyzed Bromolactonization in Lipophilic Solvent: A Solid-Liquid Phase Transfer Approach

We have developed a novel indole-catalyzed bromolactonization of olefinic acids. The reaction could be conducted in lipophilic solvent through a solid-liquid phase transfer mechanism. This catalytic protocol has been applied to the synthesis of base-sensitive bromolactones. (Chemical Equation Presented).

Monoamine oxidase-catalyzed oxidation of endo,endo-2-amino-6-[(Z)-2'-phenyl]ethenylbicyclo[2.2.1]heptane, a potential probe for a radical cation intermediate

An 11-step synthesis of endo,endo-2-amino-6-[(E)-2'-phenyl]ethenylbicyclo[2.2.1]heptane (6) and the corresponding (Z)-isomer (7) was carried out in an attempt to make a compound that could trap the purported amine radical cation intermediate during monoamine oxidase (MAO)-catalyzed oxidation of amines. The E-isomer was not a substrate for MAO, and the Z-isomer was a very poor substrate. No trapping product was observed. Possible explanations for the inability of these compounds to trap a potential radical cation intermediate are discussed. Copyright (C) 2000 Elsevier Science Ltd.