1235989-02-2

Basic information

• Product Name: (S)-4,8-dimethyl-4-phenylnon-7-en-2-one
• Synonyms: (S)-4,8-dimethyl-4-phenylnon-7-en-2-one
• CAS NO: 1235989-02-2
• Molecular Weight: 244.377
• Mol File: 1235989-02-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-4,8-dimethyl-4-phenylnon-7-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4,8-dimethyl-4-phenylnon-7-en-2-one(1235989-02-2)
• EPA Substance Registry System: (S)-4,8-dimethyl-4-phenylnon-7-en-2-one(1235989-02-2)

Safety Data

• Hazardous Substances Data: 1235989-02-2(Hazardous Substances Data)

Upstream product

• 3262-89-3 triphenylboroxine 
• 27539-94-2 (3E)-4,8-dimethylnona-3,7-dien-2-one 
• 817-88-9 4,8-dimethyl-3,7-nonadien-2-one 
• 13197-81-4 dimethyl(phenyl)aluminum 

Relevant articles and documents

Rhodium-catalyzed asymmetric 1,4-addition of aryl alanes to trisubstituted enones: Binap as an effective ligand in the formation of quaternary stereocenters

All for one and 1,4-all: Readily available aryl alanes are used in the rhodium-catalyzed asymmetric conjugate addition reaction with a variety of cyclic and acyclic enones. The enhanced reactivity of the system allows the use of the common binap ligand for the generation of quaternary benzylic stereocenters in excellent enantioselectivity (see scheme).