1236076-70-2 Usage
Boronic acid derivative
The compound is derived from boronic acid, which is a key feature in its chemical properties and reactivity.
Unique structure
The compound has a distinctive structure that includes a cyclopropane ring and a boron atom, which contribute to its versatility in organic synthesis.
Building block
It is used as a building block in the synthesis of various pharmaceuticals, agrochemicals, and materials, due to its ability to form carbon-carbon bonds and its compatibility with different chemical reactions.
Suzuki-Miyaura cross-coupling reactions
The compound is employed in this type of reaction to form carbon-carbon bonds, which is an essential step in creating complex organic molecules.
Potential applications in catalysis
2-([1,1'-bi(cyclopropan)]-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane can act as a ligand in metal-catalyzed reactions, making it a valuable component in the development of new catalytic processes.
Important roles in the development of new chemical compounds and materials
The compound's versatility and reactivity in various chemical reactions make it a crucial component in the creation of new molecules and materials for various applications.
Check Digit Verification of cas no
The CAS Registry Mumber 1236076-70-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,3,6,0,7 and 6 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1236076-70:
(9*1)+(8*2)+(7*3)+(6*6)+(5*0)+(4*7)+(3*6)+(2*7)+(1*0)=142
142 % 10 = 2
So 1236076-70-2 is a valid CAS Registry Number.
1236076-70-2Relevant articles and documents
Hydrogen Atom Transfer Induced Boron Retaining Coupling of Organoboronic Esters and Organolithium Reagents
Wang, Dinghai,Mück-Lichtenfeld, Christian,Studer, Armido
, p. 14126 - 14130 (2019)
α-Functionalization of alkyl boronic esters and homologation of aryl boronic esters by regioselective radical C(sp3)-H activation in boron-ate complexes is reported. Reaction of commercial or readily accessed aryl boronic acid pinacol esters with alkyl lithium reagents provides boron-ate complexes. Selective α-C-H abstraction by in situ generated trifluoromethyl radicals leads to radical anions that undergo electron transfer oxidation followed by 1,2-aryl/alkyl migration from boron to carbon to give the α-arylated/alkylated alkyl boronic esters. The valuable boronic ester functionality remains in the products and the cheap trifluoromethyl iodide acts as the oxidant in these C-C couplings. The 1,2-alkyl migration from boron to carbon is highly stereospecific allowing access to stereoisomerically pure boronic esters.
