124176-00-7Relevant articles and documents
Stereoselective Addition Reaction of Diethylzinc to Aldehydes, Catalyzed by Cinchona Alkaloids
Smaardijk, Ab. A.,Wynberg, Hans
, p. 135 - 137 (1987)
The cinchona alkaloid catalyzed reaction of diethylzinc and aldehydes leads to optically active alcohols having enantiomeric excesses up to 92percent.
A new chiral pyrrolidine- and pyrrolidinone-ethanols for enantioselective addition of diethylzinc to arylaldehydes
Okuyama, Yuko,Nakano, Hiroto,Igarashi, Mayumi,Kabuto, Chizuko,Hongo, Hiroshi
, p. 635 - 643 (2007/10/03)
New chiral pyrrolidineethanols and unusual type of pyrrolidinoneethanol fused bicyclo[2.2.2]octane ring systems as backbones were synthesized and were used to the addition of diethylzinc to aromatic aldehydes to afford the secondary aryl alcohols leading
Synthesis of new chiral catalysts, 2-azanorbornyloxazolidines, for enantioselective addition of diethylzinc to aldehydes
Nakano, Hiroto,Okuyama, Yuko,Iwasa, Kazuto,Hongo, Hiroshi
, p. 411 - 418 (2007/10/03)
Optically active 2-azanorbornyloxazolidines were prepared from 2-azanorbornylmethanols and catalyzed the enantioselective addition of diethylzinc to aldehydes to give optically active secondary alcohols.
