124666-23-5Relevant articles and documents
A Convenient Procedure for the Oxidation of Sterically Hindered Sulfides to Sulfoxides
Drabowicz, Jozef,Lyzwa, Piotr,Popielarczyk, Miroslaw,Mikolajczyk, Marian
, p. 937 - 938 (1990)
A selective and efficient method for the oxidation of sterically hindered sulfides to sulfoxides is described, which involves the use of hydrogen peroxide in methanol in the presence of catalytic amounts of a mixture of sulfuric acid and isoamyl, isopropy
Exploiting Substrate Diversity for Preparing Synthetically Valuable Sulfoxides via Asymmetric Hydrogenative Kinetic Resolution
Fernández-Pérez, Héctor,Grabulosa, Arnald,Lao, Joan R.,Vidal-Ferran, Anton
supporting information, (2020/07/24)
A detailed study is disclosed on the Rh-mediated hydrogenative kinetic resolution of α,β-unsaturated sulfoxides with alkyl and aryl substituents at the α-, E- and Z-positions of the double bond. This stereoselective catalytic methodology has enabled the p
Phosphinosulphoxide rhodium complexes. Synthesis, crystal structure, and catalytic chemistry of -hepta-2,5-diene>rhodium(I)trifluoromethanesulphonate and asymmetric analogues
Alcock, Nathaniel W.,Brown, John M.,Evans, Phillip L.
, p. 233 - 248 (2007/10/02)
α-Phosphinosulphoxides are readly accessible by the reaction of α-lithioalkylsulphoxides with Ph2PCl, and are stable towards internal oxygen transfer when pure.The compound Ph2PCH2S(O)Ph thus prepared was shown to form a cationic rhodium bicyclohep
