1246739-32-1

Basic information

• Product Name: 1-methyl-9,10-diphenylphenanthrene
• Synonyms: 1-methyl-9,10-diphenylphenanthrene
• CAS NO: 1246739-32-1
• Molecular Weight: 344.456
• Mol File: 1246739-32-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-methyl-9,10-diphenylphenanthrene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-9,10-diphenylphenanthrene(1246739-32-1)
• EPA Substance Registry System: 1-methyl-9,10-diphenylphenanthrene(1246739-32-1)

Safety Data

• Hazardous Substances Data: 1246739-32-1(Hazardous Substances Data)

Upstream product

• 583-55-1 1-Bromo-2-iodobenzene 
• 17933-03-8 m-tolylboronic acid 
• 501-65-5 diphenyl acetylene 
• 615-37-2 ortho-methylphenyl iodide 
• 88-65-3 2-bromobenzoic-acid 
• 107412-71-5 3'-methyl-[1,1'-biphenyl]-2-carboxylic acid 

Relevant articles and documents

Synthesis of Phenanthrenes via Palladium-Catalyzed Three-Component Domino Reaction of Aryl Iodides, Internal Alkynes, and o-Bromobenzoic Acids

A new palladium-catalyzed domino alkyne insertion/C-H activation/decarboxylation sequence has been developed, which provides an efficient approach for synthesizing a variety of functionalized phenanthrenes in moderate to good yields. The method shows broad substrate scope and good functional group tolerance by employing readily available materials, including aryl iodides, internal alkynes, and o-bromobenzoic acids, as three-component coupling partners.

Palladium-Catalyzed Regioselective Aromatic Extension of Internal Alkynes through a Norbornene-Controlled Reaction Sequence

A regioselective aromatic π-extension reaction of internal alkynes is reported. The proposed method employs three easily available components, namely aryl halides, 2-haloarylcarboxylic acids, and disubstituted acetylenes. The transformation is driven by a controlled reaction sequence of C?H activation, decarboxylation, and annulation to give poly(hetero)aromatic compounds in a site-selective fashion. Unlike in previously reported palladium-catalyzed three-component annulations, alkyne carbopalladation is the last step of this tandem reaction.