125081-35-8Relevant articles and documents
A Room Temperature Kharasch Reaction Catalyzed by Pd(0) in a Heterogeneous Aqueous System
Motoda, Dai,Kinoshita, Hidenori,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 261 - 265 (2002)
The palladium-catalyzed Kharasch reaction of alkenes and alkynes is enhanced by the use of a heterogeneous aqueous system, without the use of hydrophilic co-solvents or phase transfer catalysts. The Pd(0)-catalyzed reaction of terminal alkenes with bromot
TRIETHYLBORANE-INDUCED STEREOSELECTIVE RADICAL ADDITION OF PERFLUOROALKYL IODIDES TO ACETYLENES
Takeyama, Yoshihiro,Ichinose, Yoshifumi,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3159 - 3162 (2007/10/02)
Treatment of terminal or internal acetylenes bearing a variety of substituents with perfluoroalkyl iodides in the presence of a catalytic amount of triethylborane provides the corresponding perfluoroalkenes in good to excellent yields.The addition of perf