1250953-83-3

Basic information

• Product Name: [cobalt(II)(tetrachloroterephthalate)(dimethylformamide)2(ethanol)2
• CAS NO: 1250953-83-3
• Molecular Weight: 599.218
• Mol File: 1250953-83-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [cobalt(II)(tetrachloroterephthalate)(dimethylformamide)2(ethanol)2(CAS DataBase Reference)
• NIST Chemistry Reference: [cobalt(II)(tetrachloroterephthalate)(dimethylformamide)2(ethanol)2(1250953-83-3)
• EPA Substance Registry System: [cobalt(II)(tetrachloroterephthalate)(dimethylformamide)2(ethanol)2(1250953-83-3)

Safety Data

• Hazardous Substances Data: 1250953-83-3(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 2136-79-0 Dactal 
• 6147-53-1 cobalt(II) diacetate tetrahydrate 
• 68-12-2 N,N-dimethyl-formamide 

Relevant articles and documents

Manipulation of molecular and supramolecular structure in cobalt(II) complexes with tetrachloroterephthalate through the influence of different solvents

The reactions of cobalt acetates with tetrachloroterephthalic acid (H 2BDC-Cl4) in different solvents gave two polymeric and one mononuclear CoII complexes. X-ray single-crystal structural determination revealed that the ligand BDC-Cl4 displays a reliable bridging tecton to construct diverse supramolecular architectures through, coordinative bonds or secondary hydrogen-bonding interactions. The complexes [Co(BDC-Cl4)(DMF)2(EtOH)2]n (1) and {[Co(BDC-Cl4)(DMF)2(MeOH)2]·2DMF} n (2) demonstrate a one-dimensional (ID) coordination, motif with infinite CoII-tetrachloroterephthalate chains, which are tuned by different binding solvent systems of DMF/ethanol (EtOH) and DMF/methanol (MeOH). [CO(DMF)2(H2O)4KBDC-Cl4) (3) represents a two-dimensional (2D) metallosupramolecular network by hydrogen-bonded bridging between the aqua ligand of the mononuclear complex with the uncoordinated BDC-Cl4 solvates. The spectroscopic, thermal, and fluorescent properties of 1-3 were also investigated.