1253779-16-6Relevant articles and documents
Remote amide-directed palladium-catalyzed benzylic C-H amination with N-fluorobenzenesulfonimide
Xiong, Tao,Li, Yan,Lv, Yunhe,Zhang, Qian
supporting information; experimental part, p. 6831 - 6833 (2010/10/21)
An unprecedented remote amide-directed palladium-catalyzed intermolecular highly selective benzylic C-H amination with N-fluorobenzenesulfonimide is developed, which represents the first direct benzylic C-H amination with a non-nitrene nitrogen source. This methodology provides a novel approach to circumvent the common ortho aromatic C-H selectivity in directed palladium catalyzed C-H functionalization.