1258938-62-3

Basic information

• Product Name: 2,2'-bipyridine-1,2-dithiooxalatocopper(II)
• Synonyms: 2,2'-bipyridine-1,2-dithiooxalatocopper(II)
• CAS NO: 1258938-62-3
• Molecular Weight: 339.886
• Mol File: 1258938-62-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2'-bipyridine-1,2-dithiooxalatocopper(II)(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-bipyridine-1,2-dithiooxalatocopper(II)(1258938-62-3)
• EPA Substance Registry System: 2,2'-bipyridine-1,2-dithiooxalatocopper(II)(1258938-62-3)

Safety Data

• Hazardous Substances Data: 1258938-62-3(Hazardous Substances Data)

Upstream product

• 220632-01-9 2,2'-bipyridinedichlorocopper(II) 
• 17148-97-9 potassium 1,2-dithiooxalate 

Relevant articles and documents

2,2′-Bipyridine-1,2-dithiolate mixed ligand complexes. Synthesis, characterisation and EPR spectroscopy

A series of new 2,2′-bipyridine/1,2-dithiolate transition metal complexes has been synthesised and characterised. As 1,2-dithiolate ligands 1,2-dithiooxalate (dto) and 1,2-dithiosquarate (dtsq) were used. It follows from the IR spectra that the multidentate dithiolate ligands coordinate exclusively via their sulfur atoms forming anMN2S2 coordination sphere. The central metal ions (M) are Cu2+, Ni2+, Pd 2+, Pt2+, and Zn2+. The complex Cu II(bpy)(dto)) could be studied by EPR spectroscopy and was measured as powder, diamagnetically diluted in the isostructural NiII(bpy) (dto)) host structure. The spin density contribution calculated from the experimental parameters is compared with the electronic situation in the frontier orbitals, namely in the semi-occupied SOMO of the copper complex, derived from quantum chemical calculations on different levels (EHT and DFT).