1259091-97-8

Basic information

• Product Name: 2-(((1H-benzo[d]imidazol-2-yl)amino)(4-nitrophenyl)methyl)-3-hydroxynaphthalene-1,4-dione
• Synonyms: 2-(((1H-benzo[d]imidazol-2-yl)amino)(4-nitrophenyl)methyl)-3-hydroxynaphthalene-1,4-dione
• CAS NO: 1259091-97-8
• Molecular Weight: 440.415
• Mol File: 1259091-97-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(((1H-benzo[d]imidazol-2-yl)amino)(4-nitrophenyl)methyl)-3-hydroxynaphthalene-1,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(((1H-benzo[d]imidazol-2-yl)amino)(4-nitrophenyl)methyl)-3-hydroxynaphthalene-1,4-dione(1259091-97-8)
• EPA Substance Registry System: 2-(((1H-benzo[d]imidazol-2-yl)amino)(4-nitrophenyl)methyl)-3-hydroxynaphthalene-1,4-dione(1259091-97-8)

Safety Data

• Hazardous Substances Data: 1259091-97-8(Hazardous Substances Data)

Upstream product

• 934-32-7 1H-benzimidazol-2-amine 
• 83-72-7 2-hydroxynaphtho-1,4-quinone 
• 555-16-8 4-nitrobenzaldehdye 

Relevant articles and documents

Montmorillonite K-10 catalyzed Mannich reaction: Synthesis of aminonaphthoquinone derivatives from Lawsone

An efficient one-pot protocol for the synthesis of 2-((substituted amino)(4-phenyl)methyl)-3-hydroxy-naphthalene-1,4-dione derivatives has been developed by the three-component reaction of 2-hydroxy-naphthalene-1,4-dione, aromatic aldehydes and anilines/heterocyclic amines using montmorillonite K-10 as a catalyst. The advantages of this method include short reaction time, excellent yield and easy work-up.

Synthesis of fluorescent hydroxyl naphthalene-1,4-dione derivatives by a three-component reaction in water

An efficient one-pot synthesis of fluorescent hydroxyl naphthalene-1,4- dione derivatives by a simple, atom-economical and three-component reaction of 2- hydroxynaphthalene-1,4-dione, aromatic aldehydes and heterocyclic or carbocyclic amines in the presence of a catalytic amount of InCl3 in refluxing water is reported. The structures of the compounds were confirmed by IR, 1H NMR, 13C NMR, and elemental analysis. UV- visible absorption coefficient, maximum wavelength and fluorescence emission wavelength were measured in methanol. The products were fluorescent in solution emitting at green light (546-560 nm). The advantages of this procedure are mild reaction conditions, high yields of products, operational simplicity and easy work-up procedures. The workup of these very clean reactions involves only a filtration and simple washing step with EtOH.