1259401-57-4

Basic information

• Product Name: [Pt((c-C₅H₉)7Si₇O₁₀(OH)2)(C₆H₅)(2,2'-bipyridine)]
• Synonyms: [Pt((c-C₅H₉)7Si₇O₁₀(OH)2)(C₆H₅)(2,2'-bipyridine)]
• CAS NO: 1259401-57-4
• Molecular Weight: 1302.87
• Mol File: 1259401-57-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pt((c-C₅H₉)7Si₇O₁₀(OH)2)(C₆H₅)(2,2'-bipyridine)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pt((c-C₅H₉)7Si₇O₁₀(OH)2)(C₆H₅)(2,2'-bipyridine)](1259401-57-4)
• EPA Substance Registry System: [Pt((c-C₅H₉)7Si₇O₁₀(OH)2)(C₆H₅)(2,2'-bipyridine)](1259401-57-4)

Safety Data

• Hazardous Substances Data: 1259401-57-4(Hazardous Substances Data)

Upstream product

• 434343-90-5 (2,2'-bipyridine)(iodo)phenylplatinum(II) 
• 183387-28-2 1,3,5,7,9,11,14-heptacyclopentyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol 

Downstream Products

• 11113-50-1 boric acid 

Relevant articles and documents

Synthesis and characterization of platinasilsesquioxane complexes and their reaction with arylboronic acid

Phenyl(iodo)platinum complexes having a 2,2′-bipyridine (bpy) or 1,2-bis(diphenylphosphino)ethane (dppe) ligand react with incompletely condensed silsesquioxane (c-C5H9)7Si7O 9(OH)3 in the presence of Ag2O to yield platinasilsesquioxane complexes [Pt{(c-C5H9) 7Si7O10(OH)2}(C6H 5)(L)] (1, L = bpy; 2, L = dppe). NMR spectroscopy revealed their square-planar structures with an O-coordinated silsesquioxanate ligand and O-H...O hydrogen bonds within the ligand. Both complexes undergo transmetalation of p-methoxyphenylboronic acid to afford unsymmetrical diarylplatinum complexes [Pt(C6H4OCH3-p)(C 6H5)(L)] (3, L = bpy; 4, L = dppe).