1259926-43-6

Basic information

• Product Name: C₃₂H₂₃F₃N₄O₂S
• CAS NO: 1259926-43-6
• Molecular Weight: 584.621
• Mol File: 1259926-43-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₂H₂₃F₃N₄O₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₂H₂₃F₃N₄O₂S(1259926-43-6)
• EPA Substance Registry System: C₃₂H₂₃F₃N₄O₂S(1259926-43-6)

Safety Data

• Hazardous Substances Data: 1259926-43-6(Hazardous Substances Data)

Upstream product

• 33905-39-4 2-[(3-benzyloxyphenyl)methylamino]ethanol 
• 33905-38-3 3-(benzyloxy)-N-methylaniline 
• 1267605-77-5 2-{[3-benzyloxy-4-(2-thiophene-2-ylvinyl)-phenyl]-methylamino}ethanol 
• 1259926-42-5 5-(4-((2-hydroxyethyl)(methyl)amino)styryl)thiophene-2-carbaldehyde 
• 436097-14-2 [3-cyano-4-methyl-5-phenyl-5-(trifluoromethyl)-2(5H)-furanylidene]propanedinitrile 
• 875919-40-7 C₂₂H₃₁NO₂SSi 
• 1259926-36-7 5-[2-(2-benzyloxy-4-{[2-(tert-butyldimethylsilanyloxy)-ethyl]methylamino}phenyl)vinyl]thiophene-2-carbaldehyde 
• 1259926-35-6 [3-benzyloxy-4-(2-thiophene-2-ylvinyl)-phenyl]-[2-(tert-butyldimethylsilanyloxy)ethyl]methylamine 
• 1259926-34-5 2,2-dimethylpropionic acid 2-{[3-benzyloxy-4-(2-thiophene-2-ylvinyl)-phenyl]methylamino}ethyl ester 
• 1259926-33-4 2,2-dimethylpropionic acid 2-[(3-benzyloxy-4-formylphenyl)methylamino]ethyl ester 
• 1259926-32-3 2,2-dimethylpropionic acid 2-[(3-benzyloxyphenyl)methylamino]ethyl ester 
• 1259926-31-2 [(3-benzyloxyphenyl)methyl-amino]acetic acid ethyl ester 
• 20012-63-9 o-(benzyloxy)aniline 

Relevant articles and documents

Nonlinear optical side-chain polymers post-functionalized with high-β chromophores exhibiting large electro-optic property

Electro-optic side-chain polymers have been synthesized by the post-functionalization of methacrylate isocyanate polymers with novel phenyl vinylene thiophene vinylene bridge (FTC) nonlinear optical chromophores. For this application, FTC-based chromophores were modified in their electronic donor structure, exhibiting much larger molecular hyperpolarizabilities compared with the benchmark FTC. Of these new chromophores, absorption spectra, hyper-Rayleigh scattering experiment, and thermal analysis were carried out to confirm availability as effective nonlinear optical units for electro-optic side-chain polymers. The electro-optic coefficients (r33) of obtained polymers were investigated in the process of in situ poling by monitoring the temperature, current flow, poling field, and electro-optic signal. Compared with the nonsubstituted analogue, benxyloxy modified FTC chromophore significantly achieved higher nonlinear optical property, exhibiting molecular hyperpolarizability at 1.9 μm of 4600 × 10-30 esu and an r33 value of 150 pm/V at the wavelength of 1.31 μm. Synthesized electro-optic polymers showed high glass transition temperature (Tg), so that the temporal stability examination exhibited >78% of the electro-optic intensity remaining at 85 °C over 500 h. Copyright