126-84-1Relevant articles and documents
Solvent-free synthesis of unsaturated ketones by the Saucy-Marbet reaction using simple ammonium ionic liquid as a catalyst
Wang, Congmin,Zhao, Wenjia,Li, Haoran,Guo, Liping
, p. 843 - 847 (2009)
Simple ammonium ionic liquids are efficient catalysts in promoting Saucy-Marbet reactions of unsaturated alcohols with unsaturated ethers to afford the corresponding unsaturated ketones, eliminating the need for volatile organic solvents. The effect of th
Influence of Solvent and Counterion in the Reactions of Alkoxide Ions with the 2-Nitropropan-2-yl Radical
Russel, Glen A.,Baik, Woonphil
, p. 196 - 198 (1988)
Photostimulated free radical chain reactions between alkoxide ions derived from primary alcohols and XCMe2NO2 (X= Cl, Br, NO2, PhSO2, N3, or p-ClC6H4S) occur to produce Me2C(OR)2 by reaction involving the trapping of Me2C(NO2). by RO-, the decomposition of ROCMe2NO2.- to ROCMe2., and the oxidation of ROCMe2. to Me2C=OR+ by XCMe2NO2.
Synthesis of biodiesel without formation of free glycerol
Vol'eva,Belostotskaya,Komissarova,Koverzanova,Kurkovskaya,Usmanov,Gumerov
, p. 915 - 917 (2015/08/25)
A new approach to the synthesis of biodiesel has been developed on the basis of alcoholysis of a triglyceride in combination with acetalization of glycerol with lower carbonyl compounds or acetals derived therefrom. A model synthesis of biodiesel not involving free glycerol has been accomplished using rapeseed oil and acid catalysts, as well as without a catalyst under generation of ethanol supercritical fluid; in the latter case, monoalkyl glycerol ethers are formed in addition to the expected cyclic ketals.
Cationic gold(I) complexes: Highly efficient catalysts for the addition of alcohols to alkynes
Teles, J. Henrique,Brode, Stefan,Chabanas, Mathieu
, p. 1415 - 1418 (2007/10/03)
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