1261064-56-5Relevant articles and documents
Selective green coupling of alkynyltins and allylic halides to trienynes via a tandem double stille reaction
Meana, Isabel,Albeniz, Ana C.,Espinet, Pablo
supporting information; experimental part, p. 2887 - 2891 (2011/02/21)
The palladium-catalyzed reaction of alkynyltin compounds with allylic chlorides leads to a 2:2 coupling to give trienynes by regio- and stereoselective formation of three new C-C bonds. The reaction can be applied to different alkynyl and allylic fragments, providing a wide range of trienynes with different substitution patterns in very good yields. They can be prepared in a green way using recyclable polymeric tin alkynyls. Copyright
