1261085-79-3Relevant articles and documents
Polyhalides as Efficient and Mild Oxidants for Oxidative Carbene Organocatalysis by Radical Processes
Wu, Xingxing,Zhang, Yuexia,Wang, Yuhuang,Ke, Jie,Jeret, Martin,Reddi, Rambabu N.,Yang, Song,Song, Bao-An,Chi, Yonggui Robin
supporting information, p. 2942 - 2946 (2017/03/13)
Simple and inexpensive polyhalides (CCl4 and C2Cl6) have been found to be effective and versatile oxidants in removing electrons from Breslow intermediates under N-heterocyclic carbene (NHC) catalysis. This oxidative react
Nhc-catalyzed michael addition to α,β-unsaturated aldehydes by redox activation
De Sarkar, Suman,Studer, Armido
supporting information; experimental part, p. 9266 - 9269 (2011/02/25)
Through oxidative carbene catalysis the reactivity of enals can be reversed at the β position from the typical electrophilic to nucleophilic (homoenolate chemistry) further to electrophilic reactivity by two consecutive umpolung processes. These redox-act