1267572-87-1

Basic information

• Product Name: [(CH₃Zn)4Zn(OC(CH₃)NC₆F₅)6]
• CAS NO: 1267572-87-1
• Molecular Weight: 1731.75
• Mol File: 1267572-87-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(CH₃Zn)4Zn(OC(CH₃)NC₆F₅)6](CAS DataBase Reference)
• NIST Chemistry Reference: [(CH₃Zn)4Zn(OC(CH₃)NC₆F₅)6](1267572-87-1)
• EPA Substance Registry System: [(CH₃Zn)4Zn(OC(CH₃)NC₆F₅)6](1267572-87-1)

Safety Data

• Hazardous Substances Data: 1267572-87-1(Hazardous Substances Data)

Upstream product

• 1591-95-3 pentafluorophenyl isocyanate 
• 544-97-8 dimethyl zinc(II) 

Relevant articles and documents

Insertion reactions of heterocumulenes into Zn-C bonds: Synthesis and structural characterization of multinuclear zinc amidate complexes

Reactions of ZnMe2 with isocyanates RNCO proceeded with insertion of the isocyanate into the Zn-Me bond, giving the corresponding heteroleptic amidate complexes [MeZnOC(Me)NR]x (R = i-Pr (1), t-Bu (2)) and [{MeZn}4Zn{OC(Me)NC6F5}6] (3) in high yields. In contrast, ZnCp*2 reacts with isocyanates and isothiocyanates with formation of homoleptic complexes of the type [Zn{OC(Cp*)NR}2]2 (R = Et (4), i-Pr (5)) and [Zn{SC(Cp*)N-i-Pr}2]2 (6). 1-6 were characterized by elemental analyses, multinuclear NMR (1H, 13C, 19F) and IR spectroscopy, and single-crystal X-ray diffraction (1, 2, 5).