127073-69-2

Basic information

• Product Name: Acetonitrile, [(phenylmethyl)-2-propenylamino]-
• CAS NO: 127073-69-2
• Molecular Formula: C12H14N2
• Molecular Weight: 186.257
• Mol File: 127073-69-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetonitrile, [(phenylmethyl)-2-propenylamino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetonitrile, [(phenylmethyl)-2-propenylamino]-(127073-69-2)
• EPA Substance Registry System: Acetonitrile, [(phenylmethyl)-2-propenylamino]-(127073-69-2)

Safety Data

• Hazardous Substances Data: 127073-69-2(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 3010-05-7 benzylaminoacetonitrile 
• 106-95-6 allyl bromide 

Downstream Products

• 199472-29-2 2-(N-allyl-N-benzylamino)-3-(o-bromophenyl)propanenitrile 
• 4383-22-6 Allylbenzylamine 

Relevant articles and documents

Palladium-catalyzed chemoselective intramolecular cyclization of bromoanilinoalkenenitriles

α-(o-Bromoanilino)alkenenitriIes 1a-f and 2a-e and α-(N-alkenylamino)-β-(o-bromophenyl)-propanenitriles 7a-c and 8a-c undergo palladium-catalyzed conversion into o-(methylamino)benzonitrile 12, o-[(alkenylamino)ethenyl]benzonitriles 24a-c, N-alkenylanilines 26b, 26c, 3-benzazepines 29a, 29c, 31a and 32a, γ-carbolines 36 and pyrrolo[3,2-b]indole 45. The reactions involve intramolecular additions of arylpalladium to the cyano group and subsequent processes such as cyano group transposition, hydrolysis, electrocyclization, ethyl group transfer and oxidative aromatization. A general mechanism for the palladium-catalyzed arylation of a cyano group is proposed.