127686-75-3

Basic information

• Product Name: allyl(diphenyl)phosphine-borane
• Synonyms: allyl(diphenyl)phosphine-borane
• CAS NO: 127686-75-3
• Molecular Weight: 240.093
• Mol File: 127686-75-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: allyl(diphenyl)phosphine-borane(CAS DataBase Reference)
• NIST Chemistry Reference: allyl(diphenyl)phosphine-borane(127686-75-3)
• EPA Substance Registry System: allyl(diphenyl)phosphine-borane(127686-75-3)

Safety Data

• Hazardous Substances Data: 127686-75-3(Hazardous Substances Data)

Upstream product

• 13292-87-0 dimethyl sulfide borane 
• 1079-66-9 chloro-diphenylphosphine 
• 1730-25-2 allylmagnesium bromide 
• 107-05-1 3-chloroprop-1-ene 
• 41593-58-2 diphenylphosphineborane 
• 2049-55-0 triphenylphosphine borane 
• 14044-65-6 borane-THF 
• 104889-17-0 [PdCl₂(diphenyl-allylphosphine)2] 
• 106-95-6 allyl bromide 

Downstream Products

• 920276-29-5 diphenyltridec-2-enylphosphine borane 
• 920017-06-7 diphenyl(4-trimethylsilylbut-2-enyl)phosphine borane 
• 1262224-91-8 (3-cyclohexylpropen-3-yl)diphenylphosphine-borane 
• 1262225-05-7 (3-cyclohexylpropen-1-yl)diphenylphosphine-borane 
• 1262225-29-5 4-(diphenylboranatophosphinyl)buten-3-oic acid 
• 1262225-21-7 (4-cyclohexylidene-4-hydroxy-but-1-en-1-yl)diphenylphosphine-borane 
• 1262225-15-9 (4-hydroxy-4-(p-tolil)-but-1-en-1-yl)diphenylphosphine-borane 
• 1262225-13-7 (4-hydroxy-4-phenyl-but-1-en-1-yl)diphenylphosphine-borane 
• 1262224-85-0 diphenyl-(4-phenylbut-1-en-3-yl)phosphine-borane 
• 1262224-99-6 diphenyl-(4-phenylbut-1-en-1-yl)phosphine-borane 
• 1262225-26-2 (4-hydroxy-4-methyl-hexa-1,5-dien-1-yl)diphenylphosphine-borane 
• 1262225-30-8 (4-hydroxy-4-methyl-hexa-1,5-dien-3-yl)diphenylphosphine-borane 
• 1262225-35-3 2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester 
• 1262225-17-1 (4-hydroxy-4-(o-tolil)-but-1-en-1-yl)diphenylphosphine-borane 

Relevant articles and documents

Reactivity of allyl anions of allylphosphine-boranes towards electrophiles

The reactivity of mesomeric carbanions derived from allylphosphine-boranes varies as a function of electrophile. Small sp3-electrophiles react predominantly at the α carbon atom whereas bulky sp3- electrophiles and carbonyl compounds react mainly at the γ carbon. In the case of electron-deficient aldehydes reduction of carbonyl group and formation of the corresponding alcohols is observed. This is attributed to the weakly reducing properties of carbanions derived from allylphosphine-boranes, whose mesomeric form resembles the structure of a modified borohydride. ARKAT-USA, Inc.

Reactivity of BH3 and 9-BBN towards palladium(II) complexes of diphenylvinyl- and diphenylallyl-phosphine; X-ray structures of [PdCl2(PPh2CH2CH2CH 3)]2 and [PdCl2(PPh<

Palladium(II) chloride complexes PdCl2L2 and [PdCl2L]2 have been prepared with the phosphine ligands PPh2CH=CH2 and PPh2CH2CH=CH2. The reactions of PdClsub